New two-dimensional metal–organic frameworks constructed from 1H-benzimidazole-5,6-dicarboxylic acid with luminescent studies

• Published in: Inorganica Chimica Acta 2012-04, Vol.384, p.105-110
• Main Authors: Wang, Wei, Sun, Jia-Yin, Zhang, Dao-Jun, Song, Tian-You, Song, Wei, Zhang, Li-Ying, Chen, Yan-Li, Fan, Yong, Zhang, Ping
• Format: Article
• Language: English
• Subjects: 1H-Benzimidazole-5,6-dicarboxylic acid; Crystal structure; Lead/cadmium–organic framework; Luminescent properties
• ISSN: 0020-1693; 1873-3255
• DOI: 10.1016/j.ica.2011.11.044

Using ligand 1H-benzimidazole-5,6-dicarboxylic acid, two new 2D coordination polymers, [Pb(Hbidc)]n (1) and [Cd(Hbidc)]n (2), have been synthesized. Compound 1 is a 2D 5-connected SnS network containing a 2D [Pb(CO2)]n layer. Compound 2 possesses a 2D layer constructed of rod-shaped building blocks. [Display omitted] ► Compound 1 is a 2D 5-connected SnS network containing a 2D [Pb(CO2)]n layer. ► Compound 1 is the first MOF based on Pb(II) and Hbidc ligand. ► In compound 1, Hbidc adopts a novel bridging coordination modes (η2:η2:η1:η1:μ5). ► Compound 2 possesses a 2D layer constructed of double-stranded helices showing the opposite chirality. ► Luminescent studies show that the title compounds exhibit different fluorescence emission activity. New two-dimensional metal–organic frameworks [Pb(Hbidc)]n (1) and [Cd(Hbidc)]n (2), constructed from multidentate ligand 1H-benzimidazole-5,6-dicarboxylic acid (Hbidc), have been synthesized under hydro/solvothermal conditions and fully characterized. Compound 1 is the first lead–organic framework based on Hbidc, and displays a 5-connected SnS network which contains 2D [Pb(CO2)]n layers. The Hbidc ligand exhibits a novel coordination mode (μ5:η2:η2:η2:η1), which is reported for the first time in M-bidc frameworks. Compound 2 has a two-dimensional layer structure constructed of rod-shaped building blocks. Both the two 2D compounds are further assembled by hydrogen bonds and π–π stacking interactions into 3D supramolecular networks. Luminescent studies show that the title compounds exhibit different fluorescence emission activity at room temperature in the solid state.