Influential factors on assembly of first-row transition metal coordination polymers

The metal ion is the most important factor that influences assembly of transition metal-benzene dicarboxylic acid coordination polymers. [Display omitted] •The structures of twenty seven coordination polymers have been reported.•Metal ion is the most important influential factor for assembly.•Organi...

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Bibliographic Details
Published in:Inorganica Chimica Acta 2013-07, Vol.403, p.53-62
Main Authors: Yang, Shi-Yao, Yuan, Hong-Bo, Xu, Xiao-Bin, Huang, Rong-Bin
Format: Article
Language:English
Subjects:
Benzene dicarboxylic acid
Crystal engineering
Ion radius
Metal centre
Metal–organic framework
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Summary:The metal ion is the most important factor that influences assembly of transition metal-benzene dicarboxylic acid coordination polymers. [Display omitted] •The structures of twenty seven coordination polymers have been reported.•Metal ion is the most important influential factor for assembly.•Organic ligand is the second most important influential factor. Herein, twenty-seven coordination polymers were synthesised using Mn2+, Co2+, Ni2+, Cu2+ and Zn2+ in organic solvents. Structural analyses show that metal ions are the most important factor that influences coordination polymer assembly. Metal ions determine the type of metal centre and structural topology. The organic ligand benzene dicarboxylic acid is the second most influential factor. Synthetic conditions are not key factors in this research system.
ISSN:0020-1693
1873-3255
DOI:10.1016/j.ica.2013.03.042