Synthesis and electrochemical properties of peripheral, non-peripheral tetra [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] substituted cobalt(II), manganese(III) phthalocyanines

[Display omitted] •Synthesis of new peripherally cobalt(II), manganese(III) phthalocyanines.•Synthesis of new non-peripherally cobalt(II), manganese(III) phthalocyanines.•Investigation of electrochemical properties. In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN,...

Full description

Saved in:
Bibliographic Details
Published in:Inorganica Chimica Acta 2019-03, Vol.487, p.201-207
Main Authors: Keleş, Turgut, Biyiklioglu, Zekeriya, Gültekin, Ergün, Bekircan, Olcay
Format: Article
Language:English
Subjects:
1,2,4-Triazol
Electrochemistry
Phthalocyanine
Synthesis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] •Synthesis of new peripherally cobalt(II), manganese(III) phthalocyanines.•Synthesis of new non-peripherally cobalt(II), manganese(III) phthalocyanines.•Investigation of electrochemical properties. In this study, 4-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile ET-CN, 3-[2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy]phthalonitrile n-ET-CN and cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were synthesized for the first time. The new compounds have been characterized by FT-IR, NMR (only for ET-CN, n-ET-CN), mass and UV-Vis spectroscopy (except ET-CN, n-ET-CN) techniques. Electrochemistry of cobalt(II), manganese(III) phthalocyanines bearing [2-(3,5-diphenyl-1H-1,2,4-triazol-1-yl)ethoxy] group at peripheral, non-peripheral positions were examined by using cyclic voltammetry.
ISSN:0020-1693
1873-3255
DOI:10.1016/j.ica.2018.12.010