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Enhancing the photocatalytic performance of Co(II) and Cu(II) phthalocyanine by containing 1,3,4 thiadiazole groups in 4-nitrophenol oxidation reaction
[Display omitted] •Synthesis of new 1,3,4-thiadiazole based Co(II) and Cu(II) phthalocyanines.•Boosting photocatalytic performance of Co(II) and Cu(II) phthalocyanines on 4-nitrophenol photoxidation reaction.•Finding the convenient conditions of photoxidation with changing catalyst amount and solven...
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Published in: | Inorganica Chimica Acta 2023-03, Vol.547, p.121342, Article 121342 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | [Display omitted]
•Synthesis of new 1,3,4-thiadiazole based Co(II) and Cu(II) phthalocyanines.•Boosting photocatalytic performance of Co(II) and Cu(II) phthalocyanines on 4-nitrophenol photoxidation reaction.•Finding the convenient conditions of photoxidation with changing catalyst amount and solvent.•Working out turnover number, turnover frequency, product conversion and selectivity.
Designing an eco-friendly and low cost catalyst with high efficiency and selectivity to rapidly clean up phenolic compounds is urgently to be a priority. In this work, we have synthesized and characterized 1,3,4-thiadizaole substituted copper and cobalt phthalocyanine 4 and 5 as catalysts on 4-nitrophenol photoxidation. To determine the optimum conditions of 4-NP photoxidation, we have investigated catalyst amount and solvent effect. 2000/1 was detected as suitable substrate/catalyst ratio to give the highest product conversion (90 % for complex 4 and 95 % for complex 5). Dichloromethane, tetrahydofuran, hexane and toluene were tested as different solvent for 4-NP photoxidation and dichloromethane was found the best solvent for both catalysts. The catalytic turnover frequencies of 4 and 5 for photoxidation of 4-NP were determined to be 900 h−1 and 950 h−1, respectively, which were better values than those of the catalysts in our works. Complex 5 maintained conversion (from 95 % to 32 %) after four continuous cycles and the entire catalytic and recovery process could be achieved by separation of two phase reaction mixture. |
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ISSN: | 0020-1693 1873-3255 |
DOI: | 10.1016/j.ica.2022.121342 |