Adsorption, kinetics and thermodynamics studies of methyl orange dye sequestration through chitosan composites films

• Published in: International journal of biological macromolecules 2021-01, Vol.168, p.383-394
• Main Authors: Hussain, Shah, Kamran, Muhammad, Khan, Shahid Ali, Shaheen, Kausar, Shah, Zarbad, Suo, Hongli, Khan, Qadeer, Shah, Abdul Basit, Rehman, Waseeq Ur, Al-Ghamdi, Youssef O., Ghani, Usman
• Format: Article
• Language: English
• Subjects: Adsorption; Adsorption studies; Azo Compounds - chemistry; Azo Compounds - isolation & purification; Chitosan - chemistry; Chitosan films; Coloring Agents - chemistry; Hydrogen-Ion Concentration; Kinetics; Methyl orange dye; Spectroscopy, Fourier Transform Infrared - methods; Temperature; Thermodynamics; Water - chemistry; Water Pollutants, Chemical - chemistry; Water Purification - methods
• ISSN: 0141-8130; 1879-0003
• DOI: 10.1016/j.ijbiomac.2020.12.054

Different films comprising pure chitosan (CS) and chitosan coated sodium zeolites composites films designated as CSZ1, CSZ2, CSZ3 and CSZ4 respectively are presented here for the sequestration of MO dye. The as-synthesized films were characterized by using FSESM, XPS XRD, and TGA analysis. The sequestration of methyl orange dye (MO) was studied under various adsorption parameters i.e. pH effect, reaction temperature, catalytic dosage, interaction period, and original dye concentration in batch experiments. The adsorption power of MO dye sequestration in the presence of CSZ3 was 287 mg g−1 higher than the fine CS (201 mg g−1), and lowest for CSZ4 (173 mg g−1). The experimental data is fitted in the pseudo-second order of chemical kinetics. The Freundlich and Langmuir adsorption models were used on behalf of the analysis of experimental data that revealed multilayered adsorption of MO dye. Kinetics, equilibrium and thermodynamic process were discussed in detailed, suggesting the endothermic and spontaneous process of the adsorption of MO dye on the exterior of films. The present work is general for the MO adsorption, however, it can be applied on large scale applications and can be easily adjustable in the water purification assemblies. [Display omitted] •Synthesis of CS coated sodium zeolite films•Loading of different weight of sodium zeolite to CS film•Application in the adsorption of MO dye•Kinetics and thermodynamics studies