Simultaneous absorption of carbon dioxide and nitrogen dioxide from simulated flue gas stream using gas-liquid membrane contacting system

• Published in: International journal of greenhouse gas control 2018-10, Vol.77, p.37-45
• Main Authors: Ghobadi, Jalil, Ramirez, David, Khoramfar, Shooka, Jerman, Robert, Crane, Michele, Hobbs, Kenneth
• Format: Article
• Language: English
• Subjects: CO2 and NO2 removal; Flue gas; Gas-liquid membrane contactor; Polytetrafluoroethylene hollow fibers; Simultaneous absorption
• ISSN: 1750-5836; 1878-0148
• DOI: 10.1016/j.ijggc.2018.07.026

•Simultaneous absorption of CO2 and NO2 from a simulated flue gas stream was studied using PTFE hollow fiber membranes.•Effects of operating conditions on the gas removal and mass transfer rates of the membrane system were investigated.•Increase the inlet gas velocity enhanced the CO2 and NO2 mass transfer rates.•The presence of NO2 had a little impact on the decarbonization performance of the gas-liquid membrane system.•Long-term performance of the GLMC system confirmed the application of hollow fibers for simultaneous removal of CO2 and NO2. Membrane gas contactors are a promising alternative to conventional post-combustion carbon capture technologies. However, residuals of the other acid gas compounds can exist in the flue gas streams emitted from industrial facilities, having a notable impact on the absorption performance of the membrane system. Simultaneous removal of CO2 and NO2 from a simulated flue gas stream was carried out in a polytetrafluoroethylene (PTFE) hollow fiber gas-liquid membrane contacting (GLMC) system using different scrubbing solutions. A series of experiments were conducted to study the effects of operating conditions such as gas and liquid cross flow velocities, concentration of feed gas, absorbent nature and concentration, and long-term performance of the GLMC system on the removal efficiencies as well as mass transfer rates of CO2 and NO2. Experimental results indicated that simultaneous absorption of CO2 and NO2 were enhanced with increasing the liquid-phase cross flow velocity, decreasing gas-phase cross flow velocity, and using chemical stripping absorbents. Moreover, it was shown the sodium hydroxide to be a superior absorbent as compared to alkanolamine solutions for the co-capture of CO2 and NO2 species. It was observed that low concentrations of NO2 in the feed gas had a minimal impact on the decarbonization of GLMC system. The durability of the membrane system was also evaluated by running the simultaneous gas removal experiments over a 24-h period. The consistency of the absorption efficiency results confirmed the potential of using PTFE membrane system for the simultaneous absorption of CO2 and NO2 gases.