High-efficiency separation of a CO2/H2 mixture via hydrate formation in W/O emulsions in the presence of cyclopentane and TBAB

• Published in: International journal of hydrogen energy 2014-05, Vol.39 (15), p.7910-7918
• Main Authors: Liu, Huang, Wang, Jin, Chen, Guangjin, Liu, Bei, Dandekar, Abhijit, Wang, Bo, Zhang, Xiaoxin, Sun, Changyu, Ma, Qinglan
• Format: Article
• Language: English
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Energy; Exact sciences and technology; Fuels; Hydrate; Hydrogen; Separation; TBAB; Water-in-oil emulsion
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2014.03.094

CO2/H2 mixtures, such as integrated gasification combined cycle (IGCC) syngas, were separated via hydrate formation in water-in-oil (W/O) emulsions. The oil phase was composed of diesel and cyclopentane (CP). Span 20 was used to disperse the aqueous phase or hydrate in the oil phase, and tetra-n-butyl ammonium bromide (TBAB) was added to produce a synergistic effect with CP. The experimental results show that the presence of TBAB can remarkably increase the separation ability and improve the flow behavior of the hydrate slurry. The most suitable contents of TBAB in the aqueous phase and water in the emulsion were determined to be 0.29 mol% and 35 vol%, respectively. The maximum separation factor of CO2 over H2 was 103, which is much higher than the literature values for separating CO2/H2 gas mixture via hydrate formation. After a two-stage separation, hydrogen was enriched from 53.2 to 97.8 mol%. The influence of temperature, pressure, and the initial gas–liquid volume ratio on the separation ability and hydrate formation rate were investigated in detail. In addition, a criterion for choosing the suitable operation conditions was suggested based on both phase equilibrium and kinetic factors. Based on this criterion, the suitable operation temperature, pressure, and gas–liquid volume ratio for the separation of CO2/H2 are approximately 270.15 K, 3–5 MPa, and 80–100, respectively. •Water-in-oil (W/O) emulsion was used for the separation of CO2/H2 mixtures.•The synergistic effect of CP and TBAB was used to improve separation ability.•The maximum separation factor of CO2 over H2 reached 103.•H2 could be purified from 53.2 to 97.8 mol% through a two-stage separation.