Long-term stability of Ni–Sn porous metals for cathode current collector in solid oxide fuel cells

• Published in: International journal of hydrogen energy 2017-04, Vol.42 (17), p.12567-12573
• Main Authors: Hiraiwa, Chihiro, Tawarayama, Hiromasa, Ota, Hajime, Higashino, Takahiro, Okuno, Kazuki, Majima, Masatoshi
• Format: Article
• Language: English
• Subjects: Cathode collector; Intermediate temperature; Oxidation resistance; Porous metal; Solid oxide fuel cell
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2017.04.007

Ni–Sn porous metals with different concentrations of Sn were prepared as potential current collectors for solid oxide fuel cells (SOFCs). The weight increase of these species was evaluated after heat-treatment under elevated temperatures in air for thousands of hours to evaluate the long-term oxidation resistance. Ni–Sn porous metals with 5–14 wt% of Sn exhibited excellent oxidation resistance at 600 °C, although oxidation became significant above 700 °C. Intermetallic Ni3Sn was formed at 600 °C due to phase transformation of the initially solid solutions of Sn in Ni in the porous metals. For the porous metal with 10 wt% of Sn, the oxidation rate constant at 600 °C in air was estimated to be 8.5 × 10−14 g2 cm−4 s−1 and the electrical resistivity at 600 °C was almost constant at approximately 0.02 Ω cm2 up to an elapsed time of 1000 h. In addition, the gas diffusibility and the power-collecting ability of the porous metal were equivalent to those of a platinum mesh when applied in the cathode current collector of a SOFC operated at 600 °C. Ni–Sn porous metals with adequate contents of Sn are believed to be promising cathode current collector materials for SOFCs for operation at temperatures below 600 °C. •Ni–Sn porous metals exhibited excellent oxidation resistance at 600 °C.•The key of high oxidation resistance is to form intermetallic Ni3Sn.•Prototype SOFC using Ni-Sn porous metal has good power characteristics.•Ni-Sn porous metals are expected to be promising cathode collector for SOFC.