Highly dispersed Pd-MnOx nanoparticles supported on graphitic carbon nitride for hydrogen generation from formic acid-formate mixtures

• Published in: International journal of hydrogen energy 2017-06, Vol.42 (22), p.14865-14871
• Main Authors: Deng, Qing-Fang, Zhang, Zhuan-Fang, Cui, Feng-Juan, Jia, Li-Hua
• Format: Article
• Language: English
• Subjects: Dehydrogenation; Formic acid; Graphitic carbon nitride; Manganese; Palladium
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2017.04.294

Highly dispersed Pd and MnOx nanoparticles supported on the graphitic carbon nitride with different composition have been prepared by a simple liquid deposition-reduction method and used as an efficient FA decomposition catalyst for hydrogen generation. The catalytic activity depends on the Pd-MnOx composition of catalyst, the FA/SF ratio and the reaction temperature. The Pd-MnOx/CN-1 catalyst exhibited excellent catalytic activity for hydrogen generation with the initial TOF of 465 h−1 from formic acid-sodium formate mixture aqueous solution with a FA/SF ratio of 1:8 at 348 K. The synergetic effect between Pd nanoparticles and the carbon nitride support, the Mn/Pd ratios, the good dispersion of nanoparticles and the nature of the carbon nitride support were suggested to be responsible for the efficient catalytic performance of the Pd-MnOx/CN nanocatalysts. [Display omitted] •Manganese oxide modified palladium supported on carbon nitride have been prepared.•Introduction of manganese oxide enhanced the turnover frequency value.•The catalysts exhibit efficient catalytic activity of formic decomposition.