Cermets Ni/(Ce0.9Ln0.1O1.95) (Ln = Gd, La, Nd and Sm) prepared by solution combustion method as catalysts for hydrogen production by partial oxidation of methane

• Published in: International journal of hydrogen energy 2018-08, Vol.43 (35), p.16834-16845
• Main Authors: Alvarez-Galvan, Consuelo, Falcon, Horacio, Cascos, Vanessa, Troncoso, Loreto, Perez-Ferreras, Susana, Capel-Sanchez, Maricarmen, Campos-Martin, Jose M., Alonso, Jose Antonio, Fierro, Jose L.G.
• Format: Article
• Language: English
• Subjects: Cermets; Hydrogen; Methane; Partial oxidation; SCS
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2018.04.025

Catalysts based on Ni/(Ce0.9Ln0.1O1.95) (Ln = Gd, La, Nd and Sm) have been developed and tested for hydrogen production by partial oxidation of methane. The synthesis method (SCS, solution combustion synthesis) produces macroporous composite materials composed of ceramic (cer, Ce0.9Ln0.1O1.95) and metallic (met, Ni) phases, without the need of an activation stage prior to the catalytic reaction. The catalysts have been characterized by different techniques: X-ray diffraction, N2 adsorption-desorption, Hg porosimetry, Scanning Electron Microscopy, Temperature Programmed Reduction, H2 and O2 pulse chemisorption, X-ray photoelectron spectroscopy and Raman spectroscopy. With the exception of the lanthanum-loaded catalyst, the catalysts are highly active, selective and stable; being the one doped with gadolinium the most efficient. Correlations structure-activity point out that the excellent catalytic performance is related to the high catalytic surface area per unit mass of catalyst and to an appropriate balance of nickel dispersion to oxygen vacancies of the support. [Display omitted] •High crystallinity and porosity of Ni/Lanthanide-doped ceria prepared by SCS.•High catalytic activity per unit mass of catalyst for syngas production by CPOM.•Influence of Ni dispersion/oxygen vacancies of the support over H2 yield.•The catalyst doped with gadolinium does not show carbon formation.