Platinum nanoparticle decorated rutile titania synthesized by surfactant free hydrothermal method for visible light catalysis for dye degradation and hydrogen production study

• Published in: International journal of hydrogen energy 2019-09, Vol.44 (43), p.23959-23968
• Main Authors: Jothi Ramalingam, R., Radhika, T., Reshma Ranjan, P., Sayed, Shaban R.M., Al-lohedan, Hamad A., Meera Moydeen, A., Al-dhayan, Dhaifallah M.
• Format: Article
• Language: English
• Subjects: Methylene blue degradation; Nanoparticle; Reforming; Rutile TiO2; TEM
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2019.07.117

Rutile phase of titanium oxide and platinum nanoparticle decorated rutile titania is prepared by a surfactant free hydrothermal process in acidic condition. The pure rutile phase of TiO2 particle is forms the specific cauliflower morphology. Hydrothermal process in presence of specific acid addition led to the formation of cauli-flower shaped rutile phase of titania. The efficiency and solar assisted photo catalytic ability of these materials are tested for methylene blue degradation as well as hydrogen generation by methanol reforming process. The X-ray diffraction of pattern of pure rutile phase formation is confirmed by reported JCPDS data. The surface physico-chemical property of prepared rutile Titania is further characterized by BET, Raman and SEM analysis. The HR-TEM of the prepared samples show the reduced particle size for rutile titania and studied their morphology in detail. Solar light assisted methylene blue degradation reaction was carrying out to study the catalytic efficiency towards dye degradation and kinetic activity of the same for prepared commercial titania and pure rutile TiO2. The platinum loaded and photo deposited rutile Titania is further analyzed for hydrogen production reaction by methanol reforming process. The rate of hydrogen evolution on platinum nanoparticle photo deposited on reforming process shows more than 900 μmol/g compared to pristine rutile titania catalysts. •Surfactant free hydrothermal synthesis of Pure and Platinum nanoparticle doped rutile phase of titania fabricated.•Cauliflower like unique morphology obtained for Rutile titania.•Effective dye degradation activity obtained under visible light reaction.•Active hydrogen production catalytic activity obtained on Pt–TiO2 by photo catalytic process.