Porous flower-like nickel nitride as highly efficient bifunctional electrocatalysts for less energy-intensive hydrogen evolution and urea oxidation

• Published in: International journal of hydrogen energy 2020-05, Vol.45 (28), p.14199-14207
• Main Authors: Zhao, Zhiju, Zhao, Jun, Wang, Huibin, Li, Xuelong, Yang, Liqin, Zhao, Ziwei, Liu, Xueying, Liu, Yizhuo, Liu, Peng, Cai, Zhenyu
• Format: Article
• Language: English
• Subjects: Bifunctional; Electrocatalysis; Hydrogen evolution reaction; Ni foam; Urea oxidation reaction
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2019.11.007

Finding a suitable replacement for the high potential of anodic water electrolysis (oxygen evolution reaction (OER)) is significant for hydrogen energy storage and conversion. In this work, a simple and scalable method synthesizes a structurally unique Ni3N nanoarray on Ni foam, Ni3N-350/NF, that provides efficient electrocatalysis for the urea oxidation reaction (UOR) that transports 10 mA cm−2 at a low potential of 1.34 V. In addition, Ni3N-350/NF exhibits electro-defense electrocatalytic performance for hydrogen evolution reaction, which provides a low overpotential of 128 mV at 10 mA cm−2. As proof of concept, all-water-urea electrolysis measurement is carried out in 1 M KOH with 0.5 M Urea with Ni3N-350/NF as cathode and anode respectively. Ni3N-350/NF||Ni3N-350/NF electrode can provide 100 mA cm−2 at a voltage of only 1.51 V, 160 mV less than that of water electrolysis, which proves its commercial viability in energy-saving hydrogen production. [Display omitted] •This article shows a simple hydrothermal and calcination route to grow Ni3N-350/NF.•The synthesized electrodes were investigated for hydrogen production via water-urea electrolysis.•Ni3N-350/NF presents an excellent long-term electrochemical durability.•Ni3N-350/NF.||Ni3N-350/NF has better HER and UOR capacity compared to Pt/C||IrO2.