MOF-derived N-doped carbon coated CoP/carbon nanotube Pt-based catalyst for efficient methanol oxidation

• Published in: International journal of hydrogen energy 2020-06, Vol.45 (31), p.15630-15641
• Main Authors: zhan, Wang, Ma, Li, Gan, Mengyu, Ding, Junjie, Han, Sichen, Wei, Deying, Shen, Jun, Zhou, Chenglong
• Format: Article
• Language: English
• Subjects: CoZn-ZIF; Methanol oxidation; N-doped carbon coated CoP; Pt-based catalyst
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2020.04.032

Designing rational nanostructures of metal-organic frameworks to speed up the methanol oxidation reaction and promote their application in methanol oxidation is highly desired but still remains a great challenge. In this study, we report a novel N-doped carbon coated CoP nanoparticles/carbon nanotube Pt-based catalyst (Pt–CoP-NCZ/CNT). This composite is produced through in situ growth of CoZn-ZIF on carbon nanotubes, subsequent carbonization and phosphorization treatment and microwave-assisted Pt supporting synthesis. The high specific surface area and N-doped structure endow the prepared catalysts with ideal conditions for supporting of Pt as well as good electrical conductivity. In addition, the evaporation of Zn2+ in CoZn-ZIF not only makes a contribution to a higher specific surface area of the material but also is favorable for uniform distribution of CoP nanoparticles, which gives CoP nanoparticles an excellent co-catalysis effect. Thus, the composite exhibits wonderful mass activity in both acid (930 mA mg−1) and alkaline (3622.5 mA mg−1) environments. Furthermore, the Pt–CoP-NCZ/CNT catalyst also shows better CO tolerance and long-time stability compared with other catalysts in this study. Thereby, the fabrication of the composite catalyst makes wider application of metal-organic frameworks in methanol oxidation possible and provides inspiration for designing efficient catalysts for methanol oxidation. [Display omitted] •MOF derived CoP-NCZ/CNT composite is applied to the methanol oxidation for the first time.•Pt–CoP-NCZ/CNT catalyst exhibits excellent mass activity and CO tolerance.•The introduction of Zn into MOF is favorable to uniform dispersion of CoP NPs.