Experimental measurements of fuel and water crossover in an active DMFC

• Published in: International journal of hydrogen energy 2021-01, Vol.46 (5), p.4437-4446
• Main Authors: Li, Xianglin, Miao, Zheng, Marten, Lauren, Blankenau, Isaac
• Format: Article
• Language: English
• Subjects: Concentrated methanol solutions; DMFC; Fuel efficiency; Fuel management; Methanol crossover; Water management
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2020.11.027

This study measured polarization curves as well as the high-frequency resistance of active direct methanol fuel cell (DMFC) operates at around 80 °C with active controls of temperature, methanol concentration, airflow rate, and relative humidity. The relative humidity of the air did not have noticeable impacts on the fuel cell unless the operating temperature was near the evaporation temperature of water (100 °C). The hydrophobic water management layer (WML) between the membrane electrode assembly (MEA) and cathode air channel increases the mass transfer resistance and improves the water retention in MEA. Adding a WML increased the peak power density, decreased the ohmic resistance, and improved the fuel efficiency of the fuel cell, especially when it operated near 100 °C. This study also quantitatively measured methanol and water crossover as well as the fuel efficiency at different operating currents. The fuel efficiency increased significantly with the increase of the current density. Using a hydrophobic fuel management layer (FML) between the anode fuel channel and MEA reduced the fuel and water crossover rates and increased the ohmic resistance due to the decrease of the water content of the Nafion membrane. The FML improved fuel efficiency by reducing the methanol crossover. The combination of the FML and WML enabled the steady operation of DMFC using highly concentrated methanol solutions (up to 75 wt%). •Water and methanol flux across the MEA have been experimentally measured.•Hydrophobic components increased efficiency and improved water retention within MEA.•Fuel cell performance tested by dilute methanol was insensitive to the air humidity.•The DMFC obtained stable performance using up to 75 wt% methanol solution.