Rethinking “BLEVE explosion” after liquid hydrogen storage tank rupture in a fire

• Published in: International journal of hydrogen energy 2023-03, Vol.48 (23), p.8716-8730
• Main Authors: Cirrone, Donatella, Makarov, Dmitriy, Molkov, Vladimir
• Format: Article
• Language: English
• Subjects: Blast wave; BLEVE; CFD model; Liquid hydrogen storage; Tank rupture in fire; Validation
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2022.09.114

The underlying physical mechanisms leading to the generation of blast waves after liquid hydrogen (LH2) storage tank rupture in a fire are not yet fully understood. This makes it difficult to develop predictive models and validate them against a very limited number of experiments. This study aims at the development of a CFD model able to predict maximum pressure in the blast wave after the LH2 storage tank rupture in a fire. The performed critical review of previous works and the thorough numerical analysis of BMW experiments (LH2 storage pressure in the range 2.0–11.3 bar abs) allowed us to conclude that the maximum pressure in the blast wave is generated by gaseous phase starting shock enhanced by combustion reaction of hydrogen at the contact surface with heated by the shock air. The boiling liquid expanding vapour explosion (BLEVE) pressure peak follows the gaseous phase blast and is smaller in amplitude. The CFD model validated recently against high-pressure hydrogen storage tank rupture in fire experiments is essentially updated in this study to account for cryogenic conditions of LH2 storage. The simulation results provided insight into the blast wave and combustion dynamics, demonstrating that combustion at the contact surface contributes significantly to the generated blast wave, increasing the overpressure at 3 m from the tank up to 5 times. The developed CFD model can be used as a contemporary tool for hydrogen safety engineering, e.g. for assessment of hazard distances from LH2 storage. •CFD model to simulate maximum pressure in a blast wave after LH2 tank rupture.•Tests on rupture of LH2 tanks with pressure up to 11.3 bar are used for validation.•Hydrogen combustion at the contact surface contributes to the blast wave strength.