Blue light emitting P-Hydroxy DPQ phosphor for OLEDs

• Published in: Optik (Stuttgart) 2016-11, Vol.127 (22), p.10546-10553
• Main Authors: Mullemwar, S.Y., Zade, G.D., Kalyani, N.Thejo, Dhoble, S.J.
• Format: Article
• Language: English
• Subjects: Friedlander condensation reaction; OLEDs; Organic phosphor; Solid state lighting
• ISSN: 0030-4026; 1618-1336
• DOI: 10.1016/j.ijleo.2016.08.077

A blue light emitting novel P-Hydroxy DPQ organic phosphor based on pyrazoloquinoline derivative was synthesized by Friedlander condensation reaction of P-Hydroxyacetophenone and 2-aminobenzophenone in the presence of diphenylphosphate and m-cresol at 140°C. Structural, thermal and optical properties of the synthesized organic phosphor were characterised by recording X-ray diffraction (XRD), Fourier Transform Infrared (FT-IR) spectra, Thermo gravimetric analysis/Differential Thermal analysis (TGA/DTA), UV-absorption spectra, Photoluminescence (PL) spectra, respectively. XRD reveals its crystalline nature, while FTIR spectra reveal the formation of the quinoline complex. TGA/DTA analysis reveals significant loss in the weight of sample above room temperature, while the DTA curve of the complex shows two endothermic peaks at 99°C and 355°C and two exothermic peaks at 200°C and 380°C. The UV–vis absorption spectra of P-Hydroxy DPQ in acetic acid solution (10−3 concentration) shows a strong absorption peak λmax at 376nm with a weak shoulder at 281nm, which may be attributed due to n→π* and π→π* transitions of quinoline moieties, respectively. Optical energy band gap Eg of P-Hydroxy DPQ was measured by optical process absorption method and was found to be 2.78eV. When P-Hydroxy DPQ powder is excited at 385nm, it displays emission peak at 468nm, which falls in the blue visible region of electromagnetic radiation with (0.1391, 0.1887) as CIE coordinates. Thus this polymeric compound exhibits bright emission in blue region, indicating its potential as blue emissive material for organic light-emitting diodes (OLEDs).