Sequential extraction and reactive extraction processing of spent coffee grounds: An alternative approach for pretreatment of biodiesel feedstocks and biodiesel production

• Published in: Industrial crops and products 2018-07, Vol.117, p.359-365
• Main Authors: Tuntiwiwattanapun, Nattapong, Tongcumpou, Chantra
• Format: Article
• Language: English
• Subjects: Biodiesel; In-situ transesterification; Percolator; Sequential process; Spent coffee grounds
• ISSN: 0926-6690; 1872-633X
• DOI: 10.1016/j.indcrop.2018.03.025

[Display omitted] •A sequential pretreatment and biodiesel production process was developed.•Coffee conserve from pretreatment step was a potential source of antioxidant.•Applying isopropanol as co-solvent improved the biodiesel yield from 61 to 89%. An alternative approach to producing biodiesel from spent coffee grounds (SCGs) has been developed with methanol washing applied as a pretreatment step, followed by in-situ transesterification. Under optimal conditions, methanol washing was able to reduce the high acid value of SCGs to 0.78 mg KOH g−1 with a negligible loss of their oil content, which ended up being 11.43% by mass. Pretreated SCGs were then directly treated with a potassium methoxide solution and isopropanol as co-solvents in the in-situ transesterification process. A central composited rotatable design was applied to determine the optimal conditions for KOH concentration and proportion of isopropanol. The results showed that both KOH concentration and proportion of isopropanol had significant effects on the biodiesel yields, residual triglyceride in the biodiesel, and extraction performance (p-value