The Keggin structure complex of carbenium ions: hydrothermal synthesis and characterization of [CH 3CHCH 3] 3[PMo 12O 40]

A novel Keggin unit containing n-propylcarbocation complex, [CH 3CHCH 3] 3[PMo 12O 40], was synthesized by a hydrothermal method in the presence of CuCl 2. X-ray structure analysis has confirmed the presence of the [CH 3CHCH 3] + cations in [CH 3CHCH 3] 3[PMo 12O 40]. Its structure was also characte...

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Bibliographic Details
Published in:Inorganic chemistry communications 2004-10, Vol.7 (10), p.1100-1102
Main Authors: Jian, Fang-fang, Xiao, Hai-Lian, Zhao, Zhan-Ru, Sun, Ping-Ping, Zhao, Pu-Su
Format: Article
Language:English
Subjects:
carbocation
hydrothermal reaction
Keggin structure
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Summary:A novel Keggin unit containing n-propylcarbocation complex, [CH 3CHCH 3] 3[PMo 12O 40], was synthesized by a hydrothermal method in the presence of CuCl 2. X-ray structure analysis has confirmed the presence of the [CH 3CHCH 3] + cations in [CH 3CHCH 3] 3[PMo 12O 40]. Its structure was also characterized by thermogravimetric analysis. A novel Keggin unit containing n-propylcarbocation complex, [CH 3CHCH 3] 3[PMo 12O 40], was synthesized by a hydrothermal method in the presence of CuCl 2. X-ray structure analysis has confirmed the presence of the [CH 3CHCH 3] + cations in [CH 3CHCH 3] 3[PMo 12O 40]. Its structure was also characterized by thermogravimetric analysis.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2004.08.002