The first heterobimetallic one dimensional cyano bridged nitrosyl complex containing an alkaline earth metal: synthesis, characterization and crystal structure of the complex [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5]

The first report of a cyano bridged one dimensional Sr(II)–Fe(II) nitrosyl complex [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5] having the structure A is reported. Its interesting spectroscopic properties are described. A new Cyano bridged Sr(II)–Fe(II) nitrosyl complex [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5] (Phen...

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Bibliographic Details
Published in:Inorganic chemistry communications 2004-10, Vol.7 (10), p.1117-1119
Main Authors: RoyChowdhury, Sujoy, Komiyama, Takashi, Yukawa, Yasuhiko, Bhattacharyya, Ramgopal
Format: Article
Language:English
Subjects:
Crystal structure
Cyanide-bridged complexes
Heterobimetallic complex
Nitroprussides
Nitrosyl
Sr(II)–Fe(II)
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Summary:The first report of a cyano bridged one dimensional Sr(II)–Fe(II) nitrosyl complex [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5] having the structure A is reported. Its interesting spectroscopic properties are described. A new Cyano bridged Sr(II)–Fe(II) nitrosyl complex [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5] (Phen = 1,10 Phenanthroline and DMF = Dimethylformamide) has been synthesized and structurally characterized. The structure analysis revealed that the complex has a one-dimensional chain of [Sr(Phen) 2(DMF) 2][Fe(NO)(CN) 5] unit, which is bridged by a cyano group. In other words [Sr(Phen) 2(DMF) 2] 2+ units are bridged by [Fe(NO)(CN) 5] 2−.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2004.08.005