Synthesis and crystal structure of metal (M = Ag, Cu) crown ether with N-heterocyclic carbene linkage

Reaction of the carbene precursor 1 and Ag 2O yields the Ag(I) metal crown ether 2a. Carbene transmetalation reaction of 2a with CuI gives Cu(I) analogue 2b. The structures of 2a and 2b are determined by X-ray crystallography. Reaction of the carbene precursor 1 and Ag 2O yields the Ag(I) metal crow...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry communications 2005-11, Vol.8 (11), p.1053-1055
Main Authors: Wan, Xiang-Jian, Xu, Feng-Bo, Li, Qing-Shan, Song, Hai-Bin, Zhang, Zheng-Zhi
Format: Article
Language:English
Subjects:
Crystal structure
Metallacrown ether
N-Heterocyclic carbene
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Reaction of the carbene precursor 1 and Ag 2O yields the Ag(I) metal crown ether 2a. Carbene transmetalation reaction of 2a with CuI gives Cu(I) analogue 2b. The structures of 2a and 2b are determined by X-ray crystallography. Reaction of the carbene precursor 1 and Ag 2O yields the Ag(I) metal crown ether 2a. Carbene transmetalation reaction of 2a with CuI gives Cu(I) analogue 2b. The structures of 2a and 2b are determined by X-ray crystallography.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2005.08.007