Water aggregate: Combination of octameric water cube and (H2O)20 cluster within 3d–4f heterometallic metal–organic coordination networks

A novel water aggregate, comprised of alternate octameric water cubes and (H2O)20-cluster units, encapsulated within 3d–4f metal–organic networks [{Ln2M3(3,5-pdc)6(H2O)22}·20.5H2O]n (Ln=Sm, Eu, Gd; M=Co, Ni) is presented. A novel water aggregate, comprised of alternate octameric water cubes and (H2O...

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Bibliographic Details
Published in:Inorganic chemistry communications 2008-03, Vol.11 (3), p.314-317
Main Authors: Wu, Jing-Yun, Yin, Jen-Fu, Tseng, Tien-Wen, Lu, Kuang-Lieh
Format: Article
Language:English
Subjects:
Metal–organic networks
Water aggregate
Water cluster
Water cube
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Summary:A novel water aggregate, comprised of alternate octameric water cubes and (H2O)20-cluster units, encapsulated within 3d–4f metal–organic networks [{Ln2M3(3,5-pdc)6(H2O)22}·20.5H2O]n (Ln=Sm, Eu, Gd; M=Co, Ni) is presented. A novel water aggregate, comprised of alternate octameric water cubes and (H2O)20-cluster units, encapsulated within 3d–4f metal–organic networks [{Ln2M3(3,5-pdc)6(H2O)22}·20.5H2O]n (Ln=Sm, Eu, Gd; M=Co, Ni) is presented.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2007.12.008