Synthesis, structure, and luminescence of a two-dimensional lanthanide(III)-suberate coordination polymer resulting from dimeric secondary building units

A two-dimensional lanthanide-suberate has been synthesized via hydrothermal methods. This structure is composed of dimeric secondary building units that are extended into sheets by suberate anions. Direct photoexcitation of the lanthanide center (Eu(III) and Tb(III)) show typical emission characteri...

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Bibliographic Details
Published in:Inorganic chemistry communications 2009-02, Vol.12 (2), p.191-194
Main Authors: Lill, Daniel T. de, Tareila, Andrew M., Cahill, Christopher L.
Format: Article
Language:English
Subjects:
Coordination polymer
Hydrothermal synthesis
Lanthanide
Luminescence
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Summary:A two-dimensional lanthanide-suberate has been synthesized via hydrothermal methods. This structure is composed of dimeric secondary building units that are extended into sheets by suberate anions. Direct photoexcitation of the lanthanide center (Eu(III) and Tb(III)) show typical emission characteristics. A two-dimensional lanthanide-suberate has been synthesized via hydrothermal methods. This structure is composed of dimeric secondary building units that are extended into sheets by suberate anions. Direct photoexcitation of the lanthanide center (Eu(III) and Tb(III)) show typical emission characteristics.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2008.11.033