Synthesis and electro-catalytic properties of a dinuclear triazenido-palladium complex

The reaction of 1,3-bis[(4-chloro)benzene]triazene (HL) and [Pd(CH3CN)4]Cl2 gave a dinuclear triazenido complex Pd2L41, which has been characterized by 1H NMR spectrum and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in DMF w...

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Bibliographic Details
Published in:Inorganic chemistry communications 2013-10, Vol.36, p.245-248
Main Authors: Chu, Jing, Lv, Qi-ying, Cao, Jie-ping, Xie, Xiao-hua, Zhan, Shuzhong
Format: Article
Language:English
Subjects:
Crystal structure
Hydrogen evolution
Molecular electro-catalyst
Triazenido-palladium complex
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Summary:The reaction of 1,3-bis[(4-chloro)benzene]triazene (HL) and [Pd(CH3CN)4]Cl2 gave a dinuclear triazenido complex Pd2L41, which has been characterized by 1H NMR spectrum and X-ray crystallography. Electrochemical studies showed that complex 1 is capable of generating hydrogen from acetic acid in DMF with icat/ip~7.5. The reaction of 1,3-bis[(4-chloro)benzene]triazene (HL) and [Pd(CH3CN)4]Cl2 gave a dinuclear palladium(II) complex Pd2L4 1, which can generate hydrogen from acetic acid in DMF with icat/ip~7.5. [Display omitted] •A new dinuclear triazenido palladium(II) complex {Pd2L4} 1 is prepared.•Structure of 1 is determined by single crystal X-ray diffraction analysis.•Complex 1 is the first dinuclear palladium(II) complex that can generate hydrogen from acetic acid in organic solvent.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2013.09.007