The trigonal-bipyramidal [ReOI2(PPh3)2] — The first monomeric oxorhenium(IV) complex with monodentate ligands only

The reaction of cis-[ReVO2I(PPh3)2] with 2-(3,5-dimethylpyrazol-1-yl)benzothiazole (dbt) in ethanol led to the isolation of the trigonal-bipyramidal oxorhenium(IV) complex trans-[ReOI2(PPh3)2] (1). The complex is the first example of a monomeric oxo complex of rhenium(IV). Complex 1 was characterize...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry communications 2016-07, Vol.69, p.45-46
Main Authors: Schoultz, Xandri, Gerber, Thomas I.A., Betz, Richard
Format: Article
Language:English
Subjects:
Iodide
Monomeric
Oxorhenium(IV)
Trigonal-bipyramid
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The reaction of cis-[ReVO2I(PPh3)2] with 2-(3,5-dimethylpyrazol-1-yl)benzothiazole (dbt) in ethanol led to the isolation of the trigonal-bipyramidal oxorhenium(IV) complex trans-[ReOI2(PPh3)2] (1). The complex is the first example of a monomeric oxo complex of rhenium(IV). Complex 1 was characterized by FTIR, 1H NMR, microanalysis and single crystal X-ray diffraction. The reaction of cis-[ReVO2I(PPh3)2] with 2-(3,5-dimethylpyrazol-1-yl)benzothiazole (dbt) in ethanol led to the isolation of the trigonal-bipyramidal oxorhenium(IV) complex trans-[ReOI2(PPh3)2], which is the first example of a monomeric oxo complex of rhenium(IV). [Display omitted] •Oxorhenium(IV) monomer•Trigonal-bipyrimidal•Crystal structure
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2016.04.031