Ionic liquid-decorated Fe3O4@SiO2 nanocomposite coated on talc sheets: An efficient adsorbent for methylene blue in aqueous solution

• Published in: Inorganic chemistry communications 2020-11, Vol.121, p.108204, Article 108204
• Main Authors: Alizadeh, A., Fakhari, M., Safaei, Z., Khodeai, M.M., Repo, E., Asadi, A.
• Format: Article
• Language: English
• Subjects: Adsorption; Ionic liquid; Magnetic nanocomposite; Methylene blue; Nanoclay; Talc
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2020.108204

[Display omitted] •Fe3O4@IL-SiO2/Talc nanocomposite was prepared via co-precipitation and substitution methods.•Fe3O4@IL-SiO2/Talc nanocomposite was used for MB adsorption from in batch mode.•MB Adsorption onto Fe3O4@IL-SiO2/Talc nanocomposite was not significantly affected by pH.•Easy recovery and reusability of Fe3O4@IL-SiO2/Talc nanocomposite. Ionic liquid-modified silica-coated magnetite (Fe3O4@SiO2-IL) nanoparticles were synthesized using co-precipitation, silylation, and substitution routes, and finally immobilized on talc sheets by electrostatic interactions. The prepared Fe3O4@SiO2-IL/Talc nanocomposite was characterized by FTIR, XRD, VSM, SEM, and TEM techniques. The nanocomposite was used for adsorption of cationic methylene blue (MB) dye from the aqueous media. The effect of operating parameters, namely initial MB concentration, solution pH, and contact time on the removal rate, was investigated. Electrostatic interactions between MB ions and active sites of the nanocomposite allowed fast adsorption and nanocomposite showed higher adsorption capacity towards MB ions than talc, and Fe3O4@SiO2-IL alone. It was also found that Fe3O4@SiO2-IL/Talc nanocomposite could be used in multiple cycles using environmentally benign ethanol as a solvent. As a result, this study presents a synthesis of novel nanocomposite adsorbent for the removal of harmful organic compounds from the aqueous media, followed by easy separation and possible reuse.