Effect of Cu2+ concentration on MnFe2O4 nano-crystals in its NH3 sensing property

• Published in: Inorganic chemistry communications 2021-05, Vol.127, p.108546, Article 108546
• Main Authors: Deivatamil, D., John Abel, Martin Mark, Sivaranjani, S., Thiruneelakandan, Raghavan, Joseph Prince, Jesuraj
• Format: Article
• Language: English
• Subjects: Ammonia gas; Co-precipitation route; Gas sensor; Manganese ferrites
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2021.108546

[Display omitted] •The MnFe2O4 and Cu doped MnFe2O4 are prepared by co-precipitation method.•The structural and morphological properties of the nanoparticles were examined.•The maximum sensing efficiency was observed for 5 wt% Cu doped MnFe2O4.•The sensing percentage was found to be 78% for 5 wt% Cu doped MnFe2O4. This work is focused on the field of gas sensor for sensing the toxic gases which is highly harmful to environment. The semiconductor metal oxide nanoparticles of manganese ferrites and copper doped manganese ferrite (MnFe2O4 and Cu: MnFe2O4) was successfully developed. The characterization like crystal structure, surface morphology, optical bandgap, elemental composition and functional group analysis for the developed materials were carried out using X-ray Diffraction (XRD), Scanning electron microscope (SEM), Diffused reflectance spectroscopy (DRS), Energy dispersive X-Ray analysis (EDAX) and Fourier Transform (FT-IR) studies respectively. The ammonia gas (NH3) was taken as test gas and the sensitivity of prepared samples were analyzed with different ppm (200–400) of gas molecules at room temperature. The sensing percentage gradually improved with the increase in Cu2+ concentration also with the increase in ppm of the gas. However, the recovery time of the material is increased with increase in the ppm.