Two new multi-functional coordination polymers exhibiting photochromic behavior and amine-selective sensing capability

• Published in: Inorganic chemistry communications 2023-09, Vol.155, p.111091, Article 111091
• Main Authors: Gao, Ying, Yuan, Nannan, Zhu, Baili, Lu, Yaobo, Li, Yuanyuan, Chu, Jingying, Gao, Zeyuan, Xing, Lehong, Cui, Shuxin, Zuo, Minghui
• Format: Article
• Language: English
• Subjects: Amine; Coordination polymer; Photochromic; Viologen
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2023.111091

Compounds 1 and 2 were synthesized and characterized based on different viologen ligands. They showed different structures, photochromism and applications. [Display omitted] •Two novel multifunctional Cd-viologen coordination polymers have been synthesized.•Compounds 1 and 2 exhibit high sensitivity to UV light.•Compound 2 has the ability to detect amines. The self-assembly of Cd(II) ions with two kind of viologen ligands 1-(3,5-dicarboxybenzyl)-4,4′-bipyridinium chloride (H2L1+Cl−), 1-(3-carboxybenzyl)-4,4′-bipyridinium chloride (HL2+Cl−) and 1,3,5-benzenetricarboxylic acid (H3BTC) under solvothermal and hydrothermal conditions results in two coordination polymers, namely, {[Cd(L1)OH]}n (1) and {[Cd(L2)(HBTC)H2O]·2H2O}n (2). Due to the formation of viologen radicals, they exhibit reversible photochromism through electron transfer, and the order of light response time is 2 > 1. The time-dependent density functional theory (TDDFT)-B3LYP/lanl2dz method was used to deeply understand the donor–acceptor structures, the matching rules between L and acid parts, and the intermolecular/intramolecular atom- atom close contact based on the fraction of intercontact. Compound 1 exhibit intramolecular electron transfer. Compound 2 exhibits two electron transfer modes: intramolecular and intermolecular electron transfer. In addition, when exposed to various amines (NH3, TEA = triethylamine, MA = o-methylaniline, aniline), compound 1 displays significantly different visual color changes.