Impact of gadolinium doping on BiFeO3-PbZrO3 for energy storage applications: Structural, microstructural, and thermistor properties

• Published in: Inorganic chemistry communications 2024-08, Vol.166, p.112626, Article 112626
• Main Authors: Mallick, Priyambada, Kumari Yadav, Sandhya, Satpathy, Santosh Kumar, Behera, Banarji, Moharana, Srikanta, Sagadevan, Suresh
• Format: Article
• Language: English
• Subjects: AC conductivity; Bismuth ferrite; Density of states; Gadolinium; NTC thermistor; SDG9; XRD
• ISSN: 1387-7003; 1879-0259
• DOI: 10.1016/j.inoche.2024.112626

[Display omitted] •The solid-state reaction technique is used to prepare the Gd-doped BiFeO3-PbZrO3.•XRD data were used to compute structural characteristics, such as dislocation density, microstrain, crystallite size, and percentage of crystallinity.•The SEM micrographs indicate the spherical, tightly packed nature of materials with limited porosity.•The extent to which the composites work at high temperatures (175–400 °C) as NTC thermistors.•Based on the frequency- and temperature-dependent AC conductivity of the composites, a high density of states was calculated. The solid-state reaction technique is used to prepare the Gd-doped BiFeO3-PbZrO3 at concentrations x = 0.05, 0.10, 0.15, and 0.20 with chemical formula 0.5(BiGdxFe1-xO3)-0.5(PbZrO3). Room-temperature XRD data are used to compute structural characteristics, such as dislocation density, microstrain, crystallite size, and percentage of crystallinity. The SEM micrographs indicate the spherical, tightly packed nature of materials with limited porosity. The extent to which the composites work at high temperatures (175–400 °C) as NTC thermistors. Understanding the properties of the NTC thermistor requires the calculation of the resistor constant, sensitivity index, and activation energies. Based on the frequency- and temperature-dependent AC conductivity of the composites, a high density of states was calculated.