Characterization of copolymers of methacrylic acid with poly(ethylene glycol) methyl ether methacrylate macromonomers by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS)

• Published in: Journal of analytical and applied pyrolysis 2015-05, Vol.113, p.412-418
• Main Authors: Kusch, Peter, Rieser, Claudia, Knupp, Gerd, Mang, Thomas
• Format: Article
• Language: English
• Subjects: Copolymers of methacrylic acid with poly(ethylene glycol) methyl ether methacrylate macromonomers; GC/MS; Increments of retention indices; Poly(ethylene glycol) methyl ether methacrylate macromonomers; Pyrolysis-GC/MS
• ISSN: 0165-2370; 1873-250X
• DOI: 10.1016/j.jaap.2015.03.003

•Poly(ethylene glycol) methyl ether methacrylate (ME-PEG350-MA) macromonomers were analyzed by gas chromatography/mass spectrometry (GC/MS).•Copolymers of poly(ethylene glycol) methyl ether methacrylate (ME-PEG350-MA) macromonomers with methacrylic acid (MAA) were characterized for the first time by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS).•The separated substances were identified by using mass spectral library and by calculation of increments of the retention indices in programmed gas chromatography.•The analytical results were then used to calculate the average degrees of ethoxylation of the investigated macromonomers and copolymers. Poly(ethylene glycol) methyl ether methacrylate macromonomers (ME-PEG350-MA) and their copolymers with methacrylic acid (MAA) were characterized by gas chromatography/mass spectrometry and by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) at 550°C, respectively. The separated compounds were identified by using the mass spectral library and by calculation of increments of the retention indices in programmed gas chromatography. The obtained analytical results were then used to calculate the average degrees of ethoxylation of the investigated macromonomers and copolymers.