Modelling the chemical recycling of crosslinked poly (methyl methacrylate): Kinetics of depolymerisation

• Published in: Journal of analytical and applied pyrolysis 2019-11, Vol.144, p.104706, Article 104706
• Main Authors: Da Ros, Simoní, Braido, Rayany Stocco, de Souza e Castro, Nathany Lisbôa, Brandão, Amanda L.T., Schwaab, Marcio, Pinto, José Carlos
• Format: Article
• Language: English
• Subjects: Chemical recycling; Plastic solid waste; Poly (methyl methacrylate); Thermogravimetric analysis
• ISSN: 0165-2370; 1873-250X
• DOI: 10.1016/j.jaap.2019.104706

•Chemical recycling of crosslinked PMMA was investigated via pyrolysis.•Thermogravimetric analysis experiments were performed at different heating rates.•Kinetic parameters were estimated using nonlinear regression.•Depolymerisation kinetics was well described by a consecutive reaction pathway model. Whereas increasing plastic solid waste production constitutes one of the main challenges of modern society, mainly due to the lack of suitable recycling technologies, chemical recycling represents an attractive solution for the conversion of plastic solid waste into valuable chemical intermediates. Herein, a kinetic model for the pyrolysis of a dental industry waste, ethylene glycol dimethacrylate (EGDMA) crosslinked poly (methyl methacrylate) (PMMA), is presented for the first time. Kinetics parameters and their statistical significance have been estimated from eight non-isothermal thermogravimetric analysis (TGA) experiments with heating rates varying between 5 and 50 °C·min−1 by using nonlinear regression. Our analysis indicates that the mechanism of depolymerisation of EGDMA crosslinked PMMA is likely to involve a consecutive reaction pathway involving two steps. The developed kinetic model - containing five kinetic parameters only - was able to predict well all non-isothermal TGA runs, and was validated against isothermal TGA experiments at 400 °C.