Synthesis and properties of cellular carbon foam obtained from the pyrolysis products of a propane/butane fuel mix

• Published in: Journal of analytical and applied pyrolysis 2023-10, Vol.175, p.106189, Article 106189
• Main Authors: Raiskaya, E.A., Belskaya, O.B., Krivonos, O.I., Trenikhin, M.V., Babenko, A.V., Likholobov, V.A.
• Format: Article
• Language: English
• Subjects: Cellular carbon foam; Mesophase precursor; Petroleum sorbent; Propane-butane mix; Pyrolysis
• ISSN: 0165-2370; 1873-250X
• DOI: 10.1016/j.jaap.2023.106189

A mesophase precursor of carbon foam was synthesized by the pyrolysis of a propane-butane technical mixture; the precursor was shown to comprise polycyclic aromatic structures with the boiling point range from 200° to 400°C and above. The study revealed that the composition of the mesophase precursor can change with time, prolongation of which leads to the formation of higher molecular compounds. The formation of cellular carbon foam and its structure were studied; the possibility of obtaining closed and open cellular species was demonstrated. According to XRD, TEM and Raman spectroscopy data, the carbon material constituting the foam is nonporous and its nanostructure is typical of the carbon materials with a low ordering of graphene layers. A 70–80 nm thick carbon film in closed cellular carbon foam has a higher ordering of graphene layers and is readily removed in an air atmosphere (10 min, 850 °C) with the formation of open cellular carbon foam. The obtained carbon foam possesses high chemical and thermal stability and could be applied in the adsorption catalytic technologies. It was shown in experiments that this carbon material with a density 0.02 g•cm−3and oil capacity above 20 g•g−1 is promising for use as a regenerable petroleum sorbent. [Display omitted] •Thermopolycondensation of liquid pyrolysis products of propane-butane mix.•Effect of mesophase precursor on formation cellular carbon foam.•Carbon foam framework is nonporous with a low ordering of graphene layers.•Carbon foam as regenerable absorbent for collecting petroleum from water surface.