Mechanochemical synthesis of yttrium manganite

• Published in: Journal of alloys and compounds 2013-03, Vol.552, p.451-456
• Main Authors: Počuča-Nešić, M., Marinković Stanojević, Z., Branković, Z., Cotič, P., Bernik, S., Sousa Góes, M., Marinković, B.A., Varela, J.A., Branković, G.
• Format: Article
• Language: English
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Dielectrics, piezoelectrics, and ferroelectrics and their properties; Exact sciences and technology; Ferroelectricity and antiferroelectricity; Magnetic properties; Magnetic properties and materials; Magnetotransport phenomena, materials for magnetotransport; Manganites; Mechanochemistry; Microstructure; Multiferroic materials; Physics; Yttrium manganite
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2012.11.031

► YMnO3 was formed directly from the highly activated constituent oxides, Y2O3 and Mn2O3. ► Pure orthorhombic YMO powders were prepared (Space group Pnma) after 240min of milling time. ► The magnetic properties, as well as the nanocomposite microstructure, of the obtained YMnO3 powders were found to change as a function of milling time. ► The obtained samples are basically antiferromagnetic with weak ferromagnetism. Yttrium manganite (YMnO3) is a multiferroic material, which means that it exhibits both ferromagnetic and ferroelectric properties, so making it interesting for a variety of technological applications. In this work, single-phase YMnO3 was prepared for the first time by mechanochemical synthesis in a planetary ball mill. The YMnO3 was formed directly from the highly activated constituent oxides, Y2O3 and Mn2O3, after 60min of milling time. During prolonged milling, the growth of the particles occurred. The cumulative energy introduced into the system during milling for 60min was 86kJ/g. The X-ray powder-diffraction analysis indicates that the as-prepared samples crystallize with an orthorhombic (Pnma) YMnO3 structure. The morphology and chemical composition of the powder were investigated by SEM and FESEM. The magnetic properties of the obtained YMnO3 powders were found to change as a function of the milling time in a manner consistent with the variation in the nanocomposite microstructure.