Ultrasound-assisted growth of Zn0.2Cd0.8S nanoparticles on mesoporous P-doped graphitic carbon nitride nanosheets for superior photocatalytic activities

• Published in: Journal of alloys and compounds 2017, Vol.690, p.503-511
• Main Authors: Chen, Wei, Huang, Ting, Liu, Tian-Yu, Duan, Guo-Rong, Yang, Xu-Jie, Liu, Xiao-Heng
• Format: Article
• Language: English
• Subjects: Hydrogen evolution; P-C3N4; Photo-reduction; Zn0.2Cd0.8S
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2016.08.155

Highly-efficient visible light driven Zn0.2Cd0.8S/P-C3N4 heterostructure were successfully synthesized via ultrasound-assisted growth route. The as-prepared Zn0.2Cd0.8S/P-C3N4 nanocomposites consist of mesoporous P-C3N4 nanosheets immobilized with homogeneously dispersed Zn0.2Cd0.8S NPs. The photocatalytic applications including photoreduction of 4-nitroaniline (4-NA) and water splitting were employed to evaluate their photocatalytic activities of prepared samples. The intimate interfacial contact between the Zn0.2Cd0.8S nanoparticles and the P-C3N4 nanosheets endows these nanocomposite photocatalysts with superior visible light photocatalytic activity for both the 4-NA reduction and water splitting in comparison with pure Zn0.2Cd0.8S NPs and bare P-C3N4 NSs, especially Zn0.2Cd0.8S/P-C3N4-80. In addition, we found that Zn0.2Cd0.8S/P-C3N4-80 sample possesses excellent stability towards selective reduction of 4-NA to 4-phenylenediamine (4-PDA) during the photocatalytic running experiments. We hope that our current research on the facile fabrication and applications of Zn0.2Cd0.8S/P-C3N4 samples can provide some new insights in the design, synthesis and application of P-C3N4 based nanocomposites. The Zn0.2Cd0.8S/P-C3N4 heterostructures serves as highly-efficient visible light active photocatalysts for photo-reduction and hydrogen production, and meanwhile exhibits excellent photo-stability during the recycling runs for the reduction of 4-NA. [Display omitted] •Mesoporous P-C3N4 nanosheets were prepared by template-free strategy.•Zn0.2Cd0.8S/P-C3N4 catalysts were fabricated by ultrasound-assisted growth route.•Zn0.2Cd0.8S/P-C3N4 shows superior activities in comparison with single component.•The catalytic activities were mainly affected by the charge carrier separation.