Fabrication and characterization of nanostructured MgO·Fe2O3 composite by mechanical milling as efficient adsorbent of heavy metals

• Published in: Journal of alloys and compounds 2019-01, Vol.772, p.1030-1039
• Main Authors: Bououdina, M., Alwqyan, T.S., Khezami, L., Al-Najar, B., Shaikh, M.N., Gill, R., Modwi, A., Taha, Kamal K., Lemine, O.M.
• Format: Article
• Language: English
• Subjects: Ions adsorption; Magnesium ferrite; Magnetization; Mechanical ball milling
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2018.09.010

Nanocrystalline magnesium ferrite is synthesized by high-energy ball milling of α-Fe2O3 and MgO powders and annealed at 700, 800 and 900 °C temperatures. The Prolonged mechanical milling process has reduced the average crystallite size of MgFe2O4 to the nanometer range as confirmed by the X-ray diffraction analysis. Along with MgFe2O4 phases of α-Fe2O3 and metallic Fe were highlighted by the Rietveld XRD refinements. The scanning electron microscopy micrographs of as-milled MgO-Fe2O3 showed cauliflower-like nanostructure with narrower size distribution (≈75 nm). Furthermore, nitrogen adsorption BET analysis demonstrated flatter rather than cylindrical shaped pores with an average pore diameter in the range 24.7–66.3 nm and decreased surface area from 13.45 to 2.23 m2/g, as a function of annealing temperature. This is consistent with the increased crystallite size values obtained from XRD analysis. The magnetic study indicated a ferromagnetic behavior with low coercivity (68.68 Oe), remanence (0.840 emu/g) and saturation magnetization of 6.517 emu/g. The variation of magnetization as a function of temperature signified cations redistribution within the spinel phase MgFe2O4. The as-obtained nanopowders were tested for heavy metal removal from aqueous solutions where the data revealed improved ions removal by low temperature annealed nanoparticles especially for Ni+2 and Cd+2 indicating their potential for contaminants removal.