Enhancement of upconversion luminescence and temperature sensing performance in Er3+/Yb3+ doped Lu2O3 and Lu2O2S phosphors by incorporation of lithium ions

• Published in: Journal of alloys and compounds 2024-10, Vol.1003, p.175620, Article 175620
• Main Authors: Jin, Simeng, Ye, Renguang, Wang, Xuejiao, Jiang, Tianzhi, Wang, Juan, Hua, Youjie, Liu, Guoqing, Long, Zhiqiang, Zhang, Buqing, Bai, Gongxun, Zhang, Junjie, Xu, Shiqing
• Format: Article
• Language: English
• Subjects: Fluorescence intensity ratio; Intensity enhancement; Li+ co-doping; Temperature sensing; Upconversion luminescence
• ISSN: 0925-8388
• DOI: 10.1016/j.jallcom.2024.175620

A series of spherical Er3+/Yb3+ doped Lu2O3 and Lu2O2S phosphors co-doping with varying concentrations of Li+ (0, 1, 3, 5, and 7 mol%) were synthesized by homogeneous precipitation method followed by direct calcination or sulfurization. The crystal structure and morphology of the as-prepared phosphors were characterized by XRD, FTIR and SEM. Meanwhile, the upconversion (UC) luminescence spectra were recorded under 980 nm laser excitation at temperatures ranging from 303 to 573 K. The incorporation of lithium ions led to an enhancement of UC luminescence intensity by about 15 times at room temperature. The introduction of Li+ could also affect the temperature sensitivity of the samples. Furthermore, optical temperature sensing of the phosphors was achieved by analyzing the fluorescence intensity ratio (FIR) of thermally coupled levels (TCLs) and nonthermally coupled levels (non-TCLs). Impressively, utilizing the non-TCLs approach resulted in maximum Sa values of 8.80 %K−1 and 11.06 %K−1 for the Er3+/Yb3+/5 % Li+ doped Lu2O3 and Lu2O2S phosphors, leading to an approximately 17-fold and 23-fold increase compared to that of TCLs-based approach, respectively. The results of this work demonstrate the great potential of Er3+/Yb3+/Li+ doped Lu2O3 and Lu2O2S phosphors for optical thermometers. •Monodisperse spherical Er3+/Yb3+/Li+ doped Lu2O3 and Lu2O2S phosphors were successfully synthesized.•A simple, accurate, low cost and large-scale production method for rare earth doped Lu2O3 and Lu2O2S phosphors was proposed.•The effects of Li+ on enhancement of upconversion luminescence and thermometric performance were investigated systematically.