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Durability indicatives of hydrogel for agricultural and forestry use in saline conditions
This research tested the hypothesis that the interaction between time and salinity reduces the water absorption potential of a hydrogel – Poly (Acrylamide-co-Potassium Acrylate) and influence the degradation of residual acrylamide monomer. The experimental design was completely randomized split-plot...
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Published in: | Journal of arid environments 2021-12, Vol.195, p.104622, Article 104622 |
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container_title | Journal of arid environments |
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creator | Nascimento, Carla Danielle Vasconcelos do Feitosa, Judith Pessoa de Andrade Simmons, Robert Dias, Carlos Tadeu dos Santos Nascimento, Ícaro Vasconcelos do Mota, Jaedson Cláudio Anunciato Costa, Mirian Cristina Gomes |
description | This research tested the hypothesis that the interaction between time and salinity reduces the water absorption potential of a hydrogel – Poly (Acrylamide-co-Potassium Acrylate) and influence the degradation of residual acrylamide monomer. The experimental design was completely randomized split-plot with four replications. The treatments were time periods (30, 60, 90 and 120 days) and levels of salinity of the hydrating solution (distilled water = 0.003, 0.5; 1.5; 3.0 and 6.0 dS m−1). Swelling, hydrogel composition, and residual acrylamide monomer concentration were evaluated. The hydrogel showed lowest water absorption potential (8.1 g g−1) in a saline solution of 4.20 dS m−1 after 120 days. The C/N ratio of the hydrogel increased by up to 47% in a hydrating solution with an EC of 4.4 dS m−1 at 120 days. Additionally, there was an observed shift in the wavelength of methylene, amide, and acrylate bands, that indicates degradation. Residual acrylamide monomer concentration was |
doi_str_mv | 10.1016/j.jaridenv.2021.104622 |
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•There is an interaction time × salinity reducing the water absorption of the hydrogel•It is recommended to use the hydrogel in the lowest salinity levels possible•Up to 85% of the residual acrylamide was degraded within 120 days•The level of salinity and/or time compromise hydrogel durability.</description><identifier>ISSN: 0140-1963</identifier><identifier>EISSN: 1095-922X</identifier><identifier>DOI: 10.1016/j.jaridenv.2021.104622</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Irrigation water salinity ; Poly (Acrylamide-co-Potassium Acrylate) ; Soil conditioner</subject><ispartof>Journal of arid environments, 2021-12, Vol.195, p.104622, Article 104622</ispartof><rights>2021 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c360t-faa20a370a2ddd1df66c0500d6e2e326ec01ecd277c253ea9fab2886ada414a43</citedby><cites>FETCH-LOGICAL-c360t-faa20a370a2ddd1df66c0500d6e2e326ec01ecd277c253ea9fab2886ada414a43</cites><orcidid>0000-0002-9594-9934 ; 0000-0001-5222-3589</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Nascimento, Carla Danielle Vasconcelos do</creatorcontrib><creatorcontrib>Feitosa, Judith Pessoa de Andrade</creatorcontrib><creatorcontrib>Simmons, Robert</creatorcontrib><creatorcontrib>Dias, Carlos Tadeu dos Santos</creatorcontrib><creatorcontrib>Nascimento, Ícaro Vasconcelos do</creatorcontrib><creatorcontrib>Mota, Jaedson Cláudio Anunciato</creatorcontrib><creatorcontrib>Costa, Mirian Cristina Gomes</creatorcontrib><title>Durability indicatives of hydrogel for agricultural and forestry use in saline conditions</title><title>Journal of arid environments</title><description>This research tested the hypothesis that the interaction between time and salinity reduces the water absorption potential of a hydrogel – Poly (Acrylamide-co-Potassium Acrylate) and influence the degradation of residual acrylamide monomer. The experimental design was completely randomized split-plot with four replications. The treatments were time periods (30, 60, 90 and 120 days) and levels of salinity of the hydrating solution (distilled water = 0.003, 0.5; 1.5; 3.0 and 6.0 dS m−1). Swelling, hydrogel composition, and residual acrylamide monomer concentration were evaluated. The hydrogel showed lowest water absorption potential (8.1 g g−1) in a saline solution of 4.20 dS m−1 after 120 days. The C/N ratio of the hydrogel increased by up to 47% in a hydrating solution with an EC of 4.4 dS m−1 at 120 days. Additionally, there was an observed shift in the wavelength of methylene, amide, and acrylate bands, that indicates degradation. Residual acrylamide monomer concentration was <0.5 mg g−1 (safe for agricultural use). After 120 days up to 85% of the residual acrylamide monomer was degraded. About the water absorption potential, the results suggest that under semi-arid conditions hydrogel durability for forestry and crops applications may be impaired by the salinity of the hydrating solution.
[Display omitted]
•There is an interaction time × salinity reducing the water absorption of the hydrogel•It is recommended to use the hydrogel in the lowest salinity levels possible•Up to 85% of the residual acrylamide was degraded within 120 days•The level of salinity and/or time compromise hydrogel durability.</description><subject>Irrigation water salinity</subject><subject>Poly (Acrylamide-co-Potassium Acrylate)</subject><subject>Soil conditioner</subject><issn>0140-1963</issn><issn>1095-922X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNqFkMFKAzEURYMoWKu_IPmBqS_JTNrZKVWrUHCjoKvwmrzUDOOMJGlh_t4p1bWrB5d3LpfD2LWAmQChb5pZgzE46vYzCVKMYamlPGETAXVV1FK-n7IJiBIKUWt1zi5SagCEqCo1YR_3u4ib0IY88NC5YDGHPSXee_45uNhvqeW-jxy3Mdhdm8fvlmPnDiGlHAe-SzSSPGEbOuK2H0ty6Lt0yc48tomufu-UvT0-vC6fivXL6nl5ty6s0pALjygB1RxQOueE81pbqACcJklKarIgyDo5n1tZKcLa40YuFhodlqLEUk2ZPvba2KcUyZvvGL4wDkaAOQgyjfkTZA6CzFHQCN4eQRrX7QNFk2ygzpILkWw2rg__VfwANvh1Iw</recordid><startdate>202112</startdate><enddate>202112</enddate><creator>Nascimento, Carla Danielle Vasconcelos do</creator><creator>Feitosa, Judith Pessoa de Andrade</creator><creator>Simmons, Robert</creator><creator>Dias, Carlos Tadeu dos Santos</creator><creator>Nascimento, Ícaro Vasconcelos do</creator><creator>Mota, Jaedson Cláudio Anunciato</creator><creator>Costa, Mirian Cristina Gomes</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9594-9934</orcidid><orcidid>https://orcid.org/0000-0001-5222-3589</orcidid></search><sort><creationdate>202112</creationdate><title>Durability indicatives of hydrogel for agricultural and forestry use in saline conditions</title><author>Nascimento, Carla Danielle Vasconcelos do ; Feitosa, Judith Pessoa de Andrade ; Simmons, Robert ; Dias, Carlos Tadeu dos Santos ; Nascimento, Ícaro Vasconcelos do ; Mota, Jaedson Cláudio Anunciato ; Costa, Mirian Cristina Gomes</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c360t-faa20a370a2ddd1df66c0500d6e2e326ec01ecd277c253ea9fab2886ada414a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Irrigation water salinity</topic><topic>Poly (Acrylamide-co-Potassium Acrylate)</topic><topic>Soil conditioner</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nascimento, Carla Danielle Vasconcelos do</creatorcontrib><creatorcontrib>Feitosa, Judith Pessoa de Andrade</creatorcontrib><creatorcontrib>Simmons, Robert</creatorcontrib><creatorcontrib>Dias, Carlos Tadeu dos Santos</creatorcontrib><creatorcontrib>Nascimento, Ícaro Vasconcelos do</creatorcontrib><creatorcontrib>Mota, Jaedson Cláudio Anunciato</creatorcontrib><creatorcontrib>Costa, Mirian Cristina Gomes</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of arid environments</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nascimento, Carla Danielle Vasconcelos do</au><au>Feitosa, Judith Pessoa de Andrade</au><au>Simmons, Robert</au><au>Dias, Carlos Tadeu dos Santos</au><au>Nascimento, Ícaro Vasconcelos do</au><au>Mota, Jaedson Cláudio Anunciato</au><au>Costa, Mirian Cristina Gomes</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Durability indicatives of hydrogel for agricultural and forestry use in saline conditions</atitle><jtitle>Journal of arid environments</jtitle><date>2021-12</date><risdate>2021</risdate><volume>195</volume><spage>104622</spage><pages>104622-</pages><artnum>104622</artnum><issn>0140-1963</issn><eissn>1095-922X</eissn><abstract>This research tested the hypothesis that the interaction between time and salinity reduces the water absorption potential of a hydrogel – Poly (Acrylamide-co-Potassium Acrylate) and influence the degradation of residual acrylamide monomer. The experimental design was completely randomized split-plot with four replications. The treatments were time periods (30, 60, 90 and 120 days) and levels of salinity of the hydrating solution (distilled water = 0.003, 0.5; 1.5; 3.0 and 6.0 dS m−1). Swelling, hydrogel composition, and residual acrylamide monomer concentration were evaluated. The hydrogel showed lowest water absorption potential (8.1 g g−1) in a saline solution of 4.20 dS m−1 after 120 days. The C/N ratio of the hydrogel increased by up to 47% in a hydrating solution with an EC of 4.4 dS m−1 at 120 days. Additionally, there was an observed shift in the wavelength of methylene, amide, and acrylate bands, that indicates degradation. Residual acrylamide monomer concentration was <0.5 mg g−1 (safe for agricultural use). After 120 days up to 85% of the residual acrylamide monomer was degraded. About the water absorption potential, the results suggest that under semi-arid conditions hydrogel durability for forestry and crops applications may be impaired by the salinity of the hydrating solution.
[Display omitted]
•There is an interaction time × salinity reducing the water absorption of the hydrogel•It is recommended to use the hydrogel in the lowest salinity levels possible•Up to 85% of the residual acrylamide was degraded within 120 days•The level of salinity and/or time compromise hydrogel durability.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.jaridenv.2021.104622</doi><orcidid>https://orcid.org/0000-0002-9594-9934</orcidid><orcidid>https://orcid.org/0000-0001-5222-3589</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Irrigation water salinity Poly (Acrylamide-co-Potassium Acrylate) Soil conditioner |
title | Durability indicatives of hydrogel for agricultural and forestry use in saline conditions |
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