Liquid phase hydrogenation of α, β-unsaturated aldehydes over gold supported on iron oxides

• Published in: Journal of catalysis 2009-10, Vol.267 (1), p.50-56
• Main Authors: Lenz, Jennifer, Campo, Betiana C., Alvarez, Mariana, Volpe, María A.
• Format: Article
• Language: English
• Subjects: Catalysis; Chemistry; Colloidal state and disperse state; Exact sciences and technology; General and physical chemistry; Gold catalyst; Iron oxides; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Selective hydrogenation; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; α, β-unsaturated aldehydes
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1016/j.jcat.2009.07.012

In the liquid phase hydrogenation of crotonaldehyde and cinnamaldehyde, Au nanoparticles supported on α-Fe 2O 3 show enhanced selectivity toward the unsaturated alcohol. Goethite, hematite, and iron oxide supported on alumina are employed as supports for gold catalysts. Several samples are prepared and are characterized by TEM, TPR, and XANES. The catalysts are tested for the liquid phase hydrogenation of crotonaldehyde and cinnamaldehyde in a Batch reactor at 100 °C and at 1 MPa of H 2 employing isopropanol as the solvent. Gold particles supported on the different iron oxides are more selective than the ones supported on an inert oxide ( γ-Al 2O 3). Gold supported on hematite presents the highest selectivity toward the unsaturated alcohol. It is concluded that the promotional effect of iron on gold is neither due to the redox properties of the support nor due to the presence of charged gold particles. No dependence of selectivity to crotyl alcohol or to cinnamyl alcohol on gold particle size was observed. The origin of the improved selectivity to the unsaturated alcohol of Au/iron oxides would be related to morphological aspects of gold particles.