Upgrading of Scenedesmus obliquus oil to high-quality liquid-phase biofuel by nickel-impregnated biochar catalyst

• Published in: Journal of cleaner production 2019-02, Vol.209, p.1052-1060
• Main Authors: Ido, Alexander L., de Luna, Mark Daniel G., Ong, Dennis C., Capareda, Sergio C.
• Format: Article
• Language: English
• Subjects: Bio-oil upgrading; Biochar catalyst; Biofuel; Microalgae; Rice hull biochar; Scenedesmus obliquus
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2018.10.028

This work investigated the optimization of process parameters in the upgrading of the oil extracted from Scenedesmus obliquus microalgae using a novel nickel-impregnated biochar catalyst. The effects of temperature, dodecane-to-oil mass ratio and pressure on the upgraded liquid-phase biofuel yield were evaluated and optimized by central composite design of the response surface methodology (RSM). The model equation generated from RSM showed that dodecane-to-oil mass ratio and pressure, as well as the quadratic effects of all the three factors, were significant model terms in predicting the yield of upgraded liquid-phase biofuel. Maximum liquid biofuel yield was attained at 246.89 °C, 3.72 (w/w) dodecane-to-oil mass ratio, 3.84 MPa hydrogen pressure and 6 h processing time. Validation runs resulted in an upgraded biofuel yield of 69.4%, which was in close agreement with predicted values generated by RSM. The upgraded biofuel comprised of 100% green liquid hydrocarbons containing 94% alkanes and 6% alkenes. Its main fuel properties, such as heating value (43.78 MJ kg−1), elemental composition, density, and viscosity, exceeded those of the fatty acid methyl ester standard and were found comparable to those of petroleum diesel. More importantly, the results of the ultimate analysis and confirmed by the findings from Fourier transform infrared and gas chromatography – mass spectroscopy analyses, showed significantly low oxygen and nitrogen content and absence of sulfur in the upgraded biofuel. [Display omitted] •Novel catalyst was synthesized from rice hull biochar.•The catalyst was used to upgrade Scenedesmus obliquus oil to high-quality biofuel.•Response surface methodology was used to optimize biofuel yield.•High optimum biofuel yield at 69.4 wt. % was obtained.•The biofuel consisted of 100% green liquid hydrocarbons and HHV of 43.78 MJ kg−1.