Preparation of magnetic N-doped iron sludge based biochar and its potential for persulfate activation and tetracycline degradation

• Published in: Journal of cleaner production 2022-12, Vol.378, p.134519, Article 134519
• Main Authors: Zeng, Huiping, Li, Jianxue, Xu, Jiaxin, Qi, Wei, Hao, Ruixia, Gao, Guowei, Lin, Da, Li, Dong, Zhang, Jie
• Format: Article
• Language: English
• Subjects: Catalytic; Fe/N co-doped biochar; Iron-containing sludge; Persulfate; Tetracycline
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2022.134519

The widespread use of tetracycline (TC) is a non-negligible cause of environmental pollution, such as antibiotic resistance genes (ARGs). Economical, green and efficient treatment methods are urgently needed. In this study, the magnetic N-doped iron sludge based biochar (N-BCFe) was prepared by a one-step pyrolysis method using the iron-containing sludge from groundwater treatment plants, sycamore leaves and urea as raw materials to active persulfate (PS) for TC degradation. The results show that under the optimal experimental conditions, the removal rate of 10 mg/L TC in the N-BCFe/PS system could reach 86.56% (120 min), accompanied by a 59.9% reduction in total organic carbon (TOC), and still 63.34% of TC was removed in the third recycle experiment. Combined with EPR, free radical quenching experiments and XPS spectra, it is confirmed that there are free radicals (SO4·−, ·OH) and non-radical (1O2) pathways in N-BCFe/PS system. And the former is related to Fe doping, while the latter is attributed to N doping (nitrogen-containing functional groups). Seventeen TC intermediates were identified by LC-MS technology, and three TC degradation pathways were established accordingly. Generally, this study illustrates the considerable catalytic potential of N-BCFe and provides valuable insights into the synthesis of catalysts prepared from iron-containing sludge as feedstock. [Display omitted] •A magnetic N-doped iron sludge based BC was successfully prepared by a one-step pyrolysis method.•Fe and N were involved in the free radical and non-radical pathways of TC degradation, respectively.•N-BCFe showed good separation and reusability.