3D N-doped graphene aerogel sponge-loaded CoS2 co-catalytic Fenton system for ciprofloxacin degradation

• Published in: Journal of cleaner production 2022-12, Vol.380, p.135008, Article 135008
• Main Authors: Shi, Yueyue, Hu, Yongyou, Wang, Yao, Li, Xian, Xiao, Chun, Liu, Jingyu, Chen, Yuancai, Cheng, Jianhua, Zhu, Xiaoqiang, Wang, Guobin, Xie, Jieyun
• Format: Article
• Language: English
• Subjects: Co-catalytic; CoS2; Fe3+/Fe2+ conversion; Fenton reaction; Three-dimensional material
• ISSN: 0959-6526; 1879-1786
• DOI: 10.1016/j.jclepro.2022.135008

To avoid the loss of powder co-catalysts in metal sulfide-based co-catalytic Fenton process, we prepared a 3D N-doped graphene aerogel sponge-loaded CoS2 (SCG) and carried out a comparative study of ciprofloxacin (CIP) degradation in SCG/Fenton system, powdered CoS2/Fenton system, and conventional Fenton system. The results showed that SCG co-catalytic performance was comparable to that of powdered CoS2, the basic structure of SCG did not change after 10 times repeated experiments, and the leaching amount of Cox+ was less than 0.1 mg/L. Compared with conventional Fenton system, the content of Fe2+ in SCG/Fenton system and powdered CoS2/Fenton system increased from 1.05 mg/L to 8.2 mg/L and 7.9 mg/L, and the decomposition rate of H2O2 increased from 31.9% to 50.8% and 53.1%. The degradation rate constant of SCG/Fenton system was 0.1915 min−1, 5.7 times that of Fenton system and 1.2 times that of powdered CoS2/Fenton system, and SCG/Fenton system had a strong anti-interference ability against Cl−, NO3− and humic acid. 1O2 and ·OH played a leading role in CIP degradation. S2− and S22− on SCG surface acted as electron donors to accelerate Fe3+/Fe2+ conversion. The ecotoxicity of CIP degradation products was effectively eliminated. This study provides a reference for designing of 3D co-catalyst and a model for the application of co-catalytic Fenton system. •A novel 3D SCG co-catalyst was synthesized.•Accelerating Fe3+/Fe2+ cycle and improving H2O2 decomposition rate by SCG/Fenton system.•Metal leaching reduced and co-catalytic stability enhanced in SCG/Fenton system.•Efficient mineralization and detoxification of CIP was achieved.