Effect of temperature on the physical properties of 1-butyl-3-methylimidazolium based ionic liquids with thiocyanate and tetrafluoroborate anions, and 1-hexyl-3-methylimidazolium with tetrafluoroborate and hexafluorophosphate anions

• Published in: The Journal of chemical thermodynamics 2012-11, Vol.54, p.148-154
• Main Authors: Vakili-Nezhaad, Gholamreza, Vatani, Mostafa, Asghari, Morteza, Ashour, Ibrahim
• Format: Article
• Language: English
• Subjects: Chemical thermodynamics; Chemistry; Correlation; Empirical equations; Exact sciences and technology; General and physical chemistry; General. Theory; Ionic liquid; Physical properties; Temperature dependence; Volumetric properties
• ISSN: 0021-9614; 1096-3626
• DOI: 10.1016/j.jct.2012.03.024

► Four ionic liquids named: [BMIM][SCN], [BMIM][BF4], [HMIM][BF4], and [HMIM][PF6] are investigated. ► Density, refractive index, surface tension, dynamic viscosity, and kinematic viscosity of the ionic liquids are measured. ► The measured data was correlated with temperature finding their decrease with rising temperature. ► The volumetric properties of the ionic liquids are calculated from the experimental values of density at T=298.15K. ► Correlation between the properties was carried out by the least square method using several empirical equations. The effect of temperature on the physical properties of some ionic liquids was investigated. Density, refractive index, surface tension, dynamic and kinematic viscosities of 1-butyl-3-methylimidazolium based ionic liquids with thiocyanate and tetrafluoroborate, and 1-hexyl-3-methylimidazolium with tetrafluoroborate and hexafluorophosphate anions were measured at various temperatures (density from T=(278.15 to 363.15)K, refractive index from (293.15 to 343.15)K, surface tension from (283.15 to 333.15)K, dynamic viscosity from (283.15 to 368.15)K, and kinematic viscosity from (298.15 to 363.15)K). The volumetric properties for the ionic liquids were also calculated from the experimental values of the density at T=298.15K. The Vogel–Fulcher–Tammann (VFT) equation was applied to correlate experimental values of dynamic and kinematic viscosities as a function of temperature. As well, the relation between density and refractive index was correlated satisfactorily with several empirical equations such as Lorentz–Lorenz, Dale–Gladstone, Eykman, Oster, Arago–Biot, Newton and Modified–Eykman. Finally, the relation between surface tension and viscosity was investigated and the parachor method was used to predict density, refractive index and surface tension of the ionic liquids.