Effect of temperature on the partial molar volume, isentropic compressibility and viscosity of DL-2-aminobutyric acid in water and in aqueous sodium chloride solutions

• Published in: The Journal of chemical thermodynamics 2017-01, Vol.104, p.274-280
• Main Authors: Romero, Carmen M., Rodríguez, Diana M., Ribeiro, Ana C.F., Esteso, Miguel A.
• Format: Article
• Language: English
• Subjects: Aqueous solutions; DL-2-aminobutyric acid; Partial molar adiabatic compressibilities; Partial molar volumes; Sodium chloride aqueous solutions; Viscosities
• ISSN: 0021-9614; 1096-3626
• DOI: 10.1016/j.jct.2016.09.040

•Apparent volumes, apparent compressibilities, viscosities of DL-2-aminobutyric acid.•Effect of temperature on the values for these properties.•Hydrophobic and hydrophilic interactions and the effect of sodium chloride. Density, sound velocity and viscosity of DL-2-aminobutyric acid in water and in aqueous sodium chloride solutions have been measured at temperatures of (293.15, 298.15, 303.15, 308.15 and 313.15)K. The experimental results were used to determine the apparent molar volume and the apparent molar compressibility as a function of composition at these temperatures. The limiting values of both the partial molar volume and the partial molar adiabatic compressibility at infinite dilution of DL-2-aminobutyric acid in water and in aqueous sodium chloride solutions were determined at each temperature. The experimental viscosity values were adjusted by a least-squares method to a second order equation as proposed by Tsangaris-Martin to obtain the viscosity B coefficient which depends on the size, shape and charge of the solute molecule. The influence of the temperature on the behaviour of the selected properties is discussed in terms of both the solute hydration and the balance between hydrophobic and hydrophilic interactions between the acids and water, and the effect of the sodium chloride concentration.