Microwave-assisted synthesis of polyacrylamide-aminated graphene oxide hybrid hydrogel with improved adsorption properties

• Published in: Journal of environmental chemical engineering 2020-10, Vol.8 (5), p.104415, Article 104415
• Main Authors: Viana, Marcelo M., do Amparo, Sthéfany Z.S., Lima, Meiriane C.F.S., Lopes, Raquel C.F.G., Vasconcelos, Cláudia K.B., Caliman, Vinicius, Silva, Glaura G.
• Format: Article
• Language: English
• Subjects: Dyes; Hydrogel; Microwave synthesis; PAM
• ISSN: 2213-3437; 2213-3437
• DOI: 10.1016/j.jece.2020.104415

[Display omitted] •GO-DETA modified polyacrylamide hydrogel was prepared using microwave-assisted technique.•High capacity of methylene blue adsorption from aqueous media.•Swelling behavior of hydrogels were investigated.•The maximum adsorption capacity was 205 mg g−1. Few layers graphene oxide (GO), graphene oxide functionalized with diethylenetriamine (GO-DETA) and the hybrid of graphene oxide-diethylenetriamine and polyacrylamide (GO-DETA/PAM) hydrogel with high adsorption of methylene blue were prepared using microwave-assisted methods. TGA and XPS analysis were performed to confirm DETA molecules incorporation on GO and to identify an in-situ acrylamide polymerization with no usual chemical cross-linkers. The morphology and structure of the graphene derivative materials and hybrid gel were evaluated by TEM and SEM images. The obtained GO-DETA sheets played an important role as a cross-linker agent during the polymerization of PAM to form the hybrid GO-DETA/PAM. The results obtained showed that the GO-DETA influenced the swelling behavior and thermal properties of PAM, as well as improved its Tg, presenting a more stable PAM network in saline conditions. The hybrid hydrogel significantly improved the capacity to adsorb methylene blue (maximum adsorption capacity 205.4 mg g−1), compared to the neat PAM (maximum adsorption capacity 51.5 mg g−1). This feature demonstrates how this novel material can be used in the removal of emerging contaminants in water, for example, using a fast and reproducible synthetic method and lower quantities of adsorbent.