Rapid hydrodehalogenation of chlorinated benzoic acids using mechano-thermally prepared Raney alloy with enhanced kinetics

• Published in: Journal of environmental chemical engineering 2021-08, Vol.9 (4), p.105764, Article 105764
• Main Authors: Hegedüs, Michal, Gáborová, Katarína, Weidlich, Tomáš, Kalivoda, Pavel, Briančin, Jaroslav, Tóthová, Erika
• Format: Article
• Language: English
• Subjects: Al-Ni alloy; Chlorobenzoic acids; Herbicides; Hydrodehalogenation reaction; Mechanochemistry; Raney nickel
• ISSN: 2213-3437; 2213-3437
• DOI: 10.1016/j.jece.2021.105764

The present study reports on the degradation of chlorinated benzoic acids (CBAs), commonly present in the environment as pollutants, by a hydrodehalogenation reaction utilizing the Raney Al-Ni alloy (50:50 wt% Al:Ni). The hydrodehalogenation reaction using the Raney Al-Ni alloy has already been proven as an efficient tool for fast and efficient degradation of halogenated persistent organic pollutants (POPs). Herein, the nano-structured Raney Al-Ni alloy was prepared by an alternative mechano-thermal approach starting from pure elements in a form of powders. The prepared alloy was characterized by X-ray diffractometry, scanning electron microscopy, particle size distribution, and active surface area analyses. The properties of the material were compared with a commercial sample of the same alloy prepared by the atomization process. The activity of the synthesized alloy was evaluated as removal efficiency and a rate of dehalogenation of three different CBAs – 2-chlorobenzoic acid, 2,6-dichlorobenzoic acid, and 2,3,6-trichlorobenzoic acid (trysben); used in the past as an herbicide. Dehalogenation of all three tested CBAs yielded benzoic acid as the only product and followed the first-order reaction kinetics. Compared to the commercially available alloy, enhanced kinetics of CBAs removal was achieved, owing to the solid-state properties of the mechano-thermally prepared alloy. [Display omitted] •Nano-structured Raney Al-Ni alloy (50:50 wt% Al-Ni) can be prepared via green combined mechano-thermal approach.•Prepared alloy can effectively and rapidly remove chlorinated benzoic acids considered as environmental pollutants with long half-lives in soils and groundwaters.•Proposed hydrodehalogenation approach could be used for highly contaminated wastewaters containing chlorinated organics parameter.