A new insight on surface chemistry and redox species of transition metal (Fe, Mn) doped CeO2-SnO2/Al2O3 nanocomposites for automobile emission control

• Published in: Journal of environmental chemical engineering 2024-10, Vol.12 (5), p.113896, Article 113896
• Main Authors: Jayachandran, Varuna, Palanisami, Sanjeevi, Paneerselvam, Janardhanan, Elango, M., Chakrabortty, Sabyasachi, Ghosh, Siddhartha, Albaqami, Munirah D., Mohammad, Saikh, Sangaraju, Sambasivam
• Format: Article
• Language: English
• Subjects: Air pollution; Catalysts; Ceria-tin/alumina; Diesel exhaust treatment; Transition metal
• ISSN: 2213-3437
• DOI: 10.1016/j.jece.2024.113896

The ceria-tin/alumina mixed metal oxides (Ce/Sn =1) with different proportions of Fe & Mn dopants were synthesized and investigated in detailed approach for diesel emission reduction. The dopants created structural defects enhancing the oxygen ion mobility for exhaust treatment. The existence of surface-active oxygen sites and oxygen ion vacancy sites generated for charge compensation due to reduction of Ce4+, Sn4+ and dopants incorporation evidenced from XPS analysis. The Mn doped sample holds better physicochemical properties than Fe doped sample. The Mn doped sample with higher surface area of about 101.32 m2 g−1 exhibits greater active sites for better catalytic activity. The redox couples in the Mn-doped sample Ce4+/Ce3+, Sn4+/Sn2+, and Mn3+/Mn2+ helps in oxygen regeneration to contribute to exhaust treatment by oxygen ion conduction from bulk to the surface. This sample exhibited the 92 % of NOx reduction and proved to be a dynamic candidate for diesel emission reduction. [Display omitted] •Fe and Mn dopants insertion in CeO2-SnO2/Al2O3 sample enhances the phase stability.•Mn doped sample possesses the better physicochemical properties than Fe doped sample.•Mn doped sample shows larger surface area of 101.32 m2 g-1 with more number of active sites.•The NOx emission is drastically reduced by the Mn doped sample.