Well-matched core–shell NiO@LaMnO3/MWCNTs p-p homotype heterojunction for ascorbic acid detection

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2023-01, Vol.928, p.117080, Article 117080
• Main Authors: Zhong, Zhiyang, Xie, Aijuan, Pan, Jie, Li, Menglu, Wang, Jiaojie, Jiang, Shixin, Lin, Jiaqi, Zhu, Shichao, Luo, Shiping
• Format: Article
• Language: English
• Subjects: Ascorbic acid; Core–shell; Homotype heterojunction; NiO@LaMnO3/multi-walled carbon nanotubes
• ISSN: 1572-6657; 1873-2569
• DOI: 10.1016/j.jelechem.2022.117080

[Display omitted] Schematic diagram of the fabrication process of NiO@LaMnO3/MWCNTs/GCE and oxidation mechanisms of AA. •A novel NiO@LaMnO3/MWCNTs core–shell p-p homotype heterojunction has been designed.•NiO@LaMnO3/MWCNTs/GCE presented satisfying selectivity, repeatability, anti-interference ability.•The electrochemical signal of AA is amplified by the NiO@LaMnO3/MWCNTs core–shell heterojunction. A novel core–shell p-p homotype heterojunction based on NiO@LaMnO3 and multi-walled carbon nanotubes (NiO@LaMnO3/MWCNTs) has been designed and synthesized via electrostatic self-assembly method. The phase compositions and morphology were verified by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM). A series of electrochemical tests showed that NiO@LaMnO3/MWCNTs modified electrode had a magnifying effect on the electrochemical response signal of ascorbic acid (AA) detection. The current response is linearly increased in the range of 2.60–36.44 μmol/L with the linear regression equation being I(μA) = 0.5902C (μmol/L) + 1.4407 (R2 = 0.9909), and the detection limit (S/N = 3) being 2.41 μmol/L. Moreover, NiO@LaMnO3/MWCNTs/GCE electrochemical sensor presented satisfying selectivity, stability, repeatability, and can be used to analyze the AA concentration in real daily drinks. The relatively excellent electrocatalytic activity should be attributed to high electroactive surface area, well-matched core–shell structure and synergetic effect of p-p homotype heterojunction. This work offer applicable guidelines for the design of core–shell p-p heterojunction electrode materials for the application of electrochemical sensor.