Chemically grown Bi2MoX6 (X = O, S, and Se) nanostructures for efficient electrochemical hydrogen evolution reaction

• Published in: Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2025-01, Vol.976, p.118823, Article 118823
• Main Authors: Narwade, Sandesh H., Ghule, Balaji G., Shinde, Nanasaheb M., Suryawanshi, Rushikesh R., Kang, Kyeongnam, Jang, Ji-Hyun, Jadhav, Arvind H., Mane, Rajaram S.
• Format: Article
• Language: English
• Subjects: Bismuth molybdenum selenide; Bismuth molybdenum sulfide; Hydrogen evolution reaction; Nanosheets; Structural analysis
• ISSN: 1572-6657
• DOI: 10.1016/j.jelechem.2024.118823

•Sulfurization and selenization of Bi2MoO6 for electrochemical HER activity.•Wet chemical assisted Cost-effective and ecofriendly synthesis of electrodes.•Bi2MoSe6 shows a lower overpotential about 120 mV at 10 mA/cm2. Here, we present the fabrication of an effective and chemical bath deposition (CBD) of Bi2MoX6 (X = O, S, and Se) electrocatalyst for efficient electrochemical hydrogen evolution reaction (HER) activity. To enhance the electrochemical activity of Bi2MoO6 (BMO) electrode, the influence of sulfurization and selenization on the wet chemically synthesized BMO has been extensively studied here. These BMO, Bi2MoS6 (BMS), and Bi2MoSe6 (BMSe) nanostructured developed on nickel-foam are synthesized by a mild two-stage reaction process; a CBD following a sulfo-selenization procedure on BMO. Compared to BMO and BMS electrocatalysts, the BMSe has shown a higher HER activity through a lower overpotential about 120 mV at 10 mA cm−2 and a lower value of Tafel slope (57 mV dec−1). Surface morphology analysis endows hydrangea flower-type petals, nanosheets, and E. coli bacteria-type surface morphologies for BMO, BMS, and BMSe electrocatalysts, respectively. Thus, this article gives an easy tactic for enhancing the electrochemical HER activity of the BMO through the process of sulfurization/selenization at room temperature (25–27 °C).