Mechanical properties and grain orientation evolution of zirconium diboride-zirconium carbide ceramics

• Published in: Journal of the European Ceramic Society 2018-02, Vol.38 (2), p.391-402
• Main Authors: D’Angio’, A., Zou, J., Binner, J., Ma, Hai-Bin, Hilmas, G.E., Fahrenholtz, W.G.
• Format: Article
• Language: English
• Subjects: Borides; Electron backscattering diffraction (EBSD); High-temperature mechanical properties; Particulate reinforced composites; Ultra-high temperature ceramics (UHTC)
• ISSN: 0955-2219; 1873-619X
• DOI: 10.1016/j.jeurceramsoc.2017.09.013

The effect of ZrC on the mechanical response of ZrB2 ceramics has been evaluated from room temperature to 2000°C. Zirconium diboride ceramics containing 10vol% ZrC had higher strengths at all temperatures compared to previous reports for nominally pure ZrB2. The addition of ZrC also increased fracture toughness from ∼3.5MPam for nominally pure ZrB2 to ∼4.3MPam due to residual thermal stresses. The toughness was comparable with ZrB2 up to 1600°C, but increased to 4.6MPam at 1800°C and 2000°C. The increased toughness above 1600°C was attributed to plasticity in the ZrC at elevated temperatures. Electron back-scattered diffraction analysis showed strong orientation of the ZrC grains along the [001] direction in the tensile region of specimens tested at 2000°C, a phenomenon that has not been observed previously for fast fracture (crosshead displacement rate=4.0mmmin−1) in four point bending. It is believed that microstructural changes and plasticity at elevated temperature were the mechanisms behind the ultrafast reorientation of ZrC.