Piezoelectric properties of (1-x)BZT-xBCT system for energy harvesting applications

In this study, we investigated (1-x)Ba(Zr0.2Ti0.8)O3–x(Ba0.7Ca0.3)TiO3 lead-free piezoelectric ceramics for energy harvester applications. The (1-x)BZT-xBCT ceramic is a promising lead-free piezoelectric material in the field of piezoelectric energy harvesting. Piezoelectric and energy properties of...

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Bibliographic Details
Published in:Journal of the European Ceramic Society 2018-10, Vol.38 (13), p.4395-4403
Main Authors: Shin, Dong-Jin, Kim, Jinhwan, Koh, Jung-Hyuk
Format: Article
Language:English
Subjects:
(1-x)BZT-xBCT
Energy harvesting
Piezoelectric
Sintering temperature
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Summary:In this study, we investigated (1-x)Ba(Zr0.2Ti0.8)O3–x(Ba0.7Ca0.3)TiO3 lead-free piezoelectric ceramics for energy harvester applications. The (1-x)BZT-xBCT ceramic is a promising lead-free piezoelectric material in the field of piezoelectric energy harvesting. Piezoelectric and energy properties of (1-x)BZT-xBCT ceramics were analyzed to confirm the possibility of using them as energy-harvesting materials. Especially, the vicinity of the phase convergence region was investigated to improve their piezoelectric properties. In the phase convergence region, cubic, rhombohedral, orthorhombic, and tetragonal regions co-exist within the narrow region. Near the phase transition region between the orthorhombic and tetragonal phase, the highest piezoelectric property d33 = 464 pC/N and the highest energy density of 158.5 μJ/cm3 were observed. This output energy density of 158.5 μJ/cm3 is the recorded highest value among lead-free ceramics. We found that the optimal sintering temperature was 1475 °C and the optimal composition was BZT-0.5BCT.
ISSN:0955-2219
1873-619X
DOI:10.1016/j.jeurceramsoc.2018.05.022