The addition of (CF 3SO 2) 2CHBr to vinylidene fluoride

It has been found that a mixture of (CF 3SO 2) 2CH 2 and (CF 3SO 2) 2CBr 2 can be used instead of (CF 3SO 2) 2CHBr in the radical addition to H 2C CF 2; the 1:1 and 1:2 adducts have been isolated and characterized. An improved synthesis of (CF 3SO 2) 2CBr 2 is also reported. A mixture of (CF 3SO 2)...

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Bibliographic Details
Published in:Journal of fluorine chemistry 2006-10, Vol.127 (10), p.1324-1327
Main Authors: Winter, Rolf W., Gard, G.L.
Format: Article
Language:English
Subjects:
Bis(trifluoromethanesulfonyl) derivatives
Vinylidene adducts with (CF 3SO 2) 2CHBr
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Summary:It has been found that a mixture of (CF 3SO 2) 2CH 2 and (CF 3SO 2) 2CBr 2 can be used instead of (CF 3SO 2) 2CHBr in the radical addition to H 2C CF 2; the 1:1 and 1:2 adducts have been isolated and characterized. An improved synthesis of (CF 3SO 2) 2CBr 2 is also reported. A mixture of (CF 3SO 2) 2CH 2 and (CF 3SO 2) 2Br 2 can be used instead of (CF 3SO 2) 2CHBr in the radical addition to H 2C CF 2. New 1:1 and 1:2 adducts have been isolated and characterized. In addition, an improved synthesis of (CF 3SO 2) 2Br 2 has been found. ▪
ISSN:0022-1139
1873-3328
DOI:10.1016/j.jfluchem.2006.05.023